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Reactions of 3-amino-4-methylfurazan with nitrating agents

“…It was only reported that the use of traditional HNO 3 /H 2 SO 4 mixtures is accompanied by side nitrolysis of the N-CH bond, resulting in the formation of primary nitraminofurazans. 10 The information on nitration of primary aminofurazans is limited. Nitramines can be obtained by reactions with N 2 O 5 , 11 HNO 3 (see Refs 5,[12][13][14][15], or NaNO 3 /H 2 SO 4 (see Ref.…”

“…Nitramines can be obtained by reactions with N 2 O 5 , 11 HNO 3 (see Refs 5,[12][13][14][15], or NaNO 3 /H 2 SO 4 (see Ref. 10), HNO 3 /H 2 SO 4 (see Refs 5,13), and HNO 3 /AcOH (see Ref. 16) mixtures.…”

Electrooxidative coupling of salts of nitro compounds with halide, nitrite, cyanide, and phenylsulfinate anions

“…Methyl (1 nitrocyclohexyl)carboxyimidate (14). 47 13 C NMR, δ: 22.18 (C(3)); 24.24 (C(4)); 32.73 (C(2)); 54.28 (ОMе); 92.35 (C(1)); 167.28 (C=N).…”

Electrochemical synthesis of geminal azidonitro compounds

“…The resulting Na salts of 1 azido 1 nitroalkanes are very unstable; for instance, the half life period of the Na salt of 1 azido 1 nitroethane at pH 10 is 10 min, nitrogen evolving on its decomposition. 2 This assumption was supported by successful electrooxidative coupling of salts of primary nitroalkanes with NaN 3 in a divided cell with 0.1 M H 2 SO 4 as a catholyte (with 0.1 M NaOH as a catholyte, no 1 azido 1 nitroalkanes were obtained). Unlike salts of primary nitroalkanes 1a-c, salts of secondary nitro compounds, namely, 2 nitropropane (1d), 4 nitroheptan 2 one (1e), nitrocyclohexane (1g), nitro cycloheptane (1h), and 2 nitronorbornane (1i), can react with NaN 3 to form the corresponding geminal azidonitro compounds under the conditions of two phase undivided electrolysis.…”