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Highly selective formation of benzophenone (99.1%) from diphenylmethane is reported for the first time using H2O2 (30%) as an oxidant and Co/MCM-41 as the catalyst.

Metal–organic framework aerogels (MOAs) embedded with CdS (CdS/MOA(Cr)) synthesized via a facile one-pot solvothermal method have a larger surface area than pristine MOA(Cr) and the post-synthesized composite.

A series of ceria-zirconia solid solutions were synthesized using tobacco leaves, stems and stem-silks as biotemplates. A combination of physicochemical techniques such as powder X-ray diffraction (XRD), N 2 adsorption/desorption measurement, scanning electron microscopy (SEM), and transmission electron microscopy (TEM) were used to characterize the as-synthesized samples. The results show that the morphologies of the templates were well replicated in the obtained ceria-zirconia solid solutions. Catalytic oxidation activities of CO over the ceria-zirconia solid solutions were then investigated. The catalyst templated by tobacco stem-silk exhibited higher conversion of CO at lower temperature than that of ceria-zirconia solid solutions templated by tobacco leaves and stems or without templates due to its special morphology. The catalyst even showed similar CO conversion when compared to ceria-zirconia solid solutions doped with 1.0 wt % noble metals such as Pt, Ag and Au. The results highlighted the advantages of using tobacco as biotemplate.