Metamaterials (MMs) offer great potential for achieving optical absorption due to their novel electromagnetic properties. MM absorbers can overcome the thickness limitation and provide excellent absorption performance over the wide frequency range, thereby enable the swift emergence of some promising applications. Moreover, the optical sensors based on MM absorbers have shown great potential in several fields. This review concentrates on the recent progresses in MM-based optical absorbers and spectral sensing. We present four aspects of MM-based optical absorption: the metal-insulation-metal arrangements, the optical coherence, the functional materials, and some novel approaches. Also, we present three aspects of MM-based optical sensing: the refractive index sensing, gas and molecule sensing, and surface-enhanced Raman scattering. Finally, the current challenges and prospects in device designs, fabrications have been discussed. This review is with the purpose to give a generalized knowledge of MMs for optical absorption and sensing, thus inspiring the investigations on MMs for other devices and their practical applications.
Here, we propose a thermally stable and high-reflectivity Ni/Rh/Ni/Au p-type electrode for AlGaN-based deep-ultraviolet (DUV) flip-chip light-emitting diodes (FCLEDs). We discover that the reflectance of Ni/Au electrode deteriorated significantly after rapid thermal annealing. Experiments show that Ni and Au agglomerate at high temperatures, and more incident photons traverse the gaps between the agglomerates, leading to a decrease in reflectance of Ni/Au after annealing. In contrast, the proposed Ni/Rh/Ni/Au p-type electrode shows remarkable thermal stability as a result of the suppression of Ni agglomeration by the Rh layer at high temperatures. Besides, due to the higher reflectivity of the Ni/Rh/Ni/Au electrode and its lower specific contact resistivity formed with p-GaN, the external quantum efficiency and wall-plug efficiency of a DUV FCLED with Ni/Rh/Ni/Au electrode are increased by 13.94% and 17.30% in comparison with the one with Ni/Au electrode at an injection current of 100 mA. The Ni/Rh/Ni/Au electrode effectively solves the long-standing dilemma of efficiency degradation of DUV FCLEDs with a Ni/Au electrode after high-temperature annealing.
Herein, a tunable thermal-optical ultra-narrowband grating absorber is realized. Four ultra-sharp absorption peaks in the infrared region are achieved with the absorption efficiency of 19.89%, 98.41%, 99.14%, and 99.99% at 1144.34 nm, 1190.92 nm, 1268.58 nm, and 1358.70 nm, respectively. Benefiting from an extremely narrow bandwidth (0.27 nm), a maximum Q-factor over 4400 is obtained for the absorber. Moreover, the spectral response can be artificially tuned by controlling the temperature via the strong thermo-optic effect of silicon resonator. The high absorption contrast ratio of 23 dB is demonstrated by only increasing the temperature by 10 °C, showing an order of magnitude better than that of the previously demonstrated performance in the infrared image contrast manipulation. Also, the absorption intensity can be precisely regulated via tuning the polarization state of incident light. Strong tunability extending to temperature and polarization states makes this metasurface promising for applications in a high-performance switch, notch filter, modulator, etc.
Designing and manufacturing cost-effective absorbers that can cover the full-spectrum of solar irradiation is still critically important for solar harvesting. Utilizing control of the lightwave reflection and transmission, metamaterials realize high absorption over a relatively wide bandwidth. Here, a truncated circular cone metasurface (TCCM) composed of alternating multiple layers of titanium (Ti) and silicon dioxide (SiO2) is presented. Enabled by the synergetic of surface plasmon resonances and Fabry–Pérot resonances, the TCCM simultaneously achieves high absorptivity (exceed 90%), and absorption broadband covers almost the entire solar irradiation spectrum. In addition, the novel absorber exhibits great photo-thermal property. By exploiting the ultrahigh melting point of Ti and SiO2, high-efficiency solar irradiation absorption and heat release have been achieved at 700 °C when the solar concentration ratio is 500 (i.e., incident light intensity at 5 × 105 W/m2). It is worth noting that the photo-thermal efficiency is almost unchanged when the incident angle increases from 0° to 45°. The outstanding capacity for solar harvesting and light-to-heat reported in this paper suggests that TCCM has great potential in photothermal therapies, solar desalination, and radiative cooling, etc.
Despite the fact that solar energy has been widely used as a renewable and clean energy source for decades, when designing solar irradiation absorbers one is generally confronted with the dilemma of choosing between higher absorption but narrowband or broadband but lower absorption, which has greatly limited the development of the solar energy industry. In this work, a gradient cavity-thin-film metasurface (GCM) made up of alternating multiple layers of titanium (Ti) and silicon dioxide (SiO2) exhibits ultra-broadband strong absorption in 354–2980 nm. The operating bandwidth covers the dominating portion of the solar irradiation spectrum. The absorption spectrum can be manipulated by adjusting the structural parameters of the unit cell. It is worth noting that the spectrally weighted solar absorption efficiency reaches 98.28% under the AM 1.5G illumination. This impressive near-unity absorption could be attributed to multiple light–matter interactions including surface plasmon resonances, cavity resonance, and the intrinsic spectral responses of multi-layer refractory material. In addition, the absorption response is insensitive to the incident angle and polarization states. These high performances provide the GCM with great potential for practical applications in solar thermal energy harvesting and photothermal conversion, etc.
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