Ti has a high affinity for hydrogen and are typical hydride formers. Ti-hydride are brittle phases which probably cause premature failure of Ti-alloys. Here, we used atom probe tomography and electron microscopy to investigate the hydrogen distribution in a set of specimens of commercially pure Ti, model and commercial Ti-alloys. Although likely partly introduced during specimen preparation with the focused-ion beam, we show formation of Ti-hydrides along α grain boundaries and α/β phase boundaries in commercial pure Ti and α+β binary model alloys. No hydrides are observed in the α phase in alloys with Al addition or quenched-in Mo supersaturation.
Abstract. Here we discuss approaches for designing microstructures in steels and titanium alloys by manipulating the segregation content and the structural state of lattice defects. Different mechanisms can be utilized in that context, such as for instance site specific segregation as described by the Gibbs isotherm and the generalized defectant concept, confined phase transformation phenomena and the formation of complexions, i.e. confined chemical and structural states at lattice defects.
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