A surfactantless, one-pot reduction approach for Pd@Pt core–shell nano-stars on reduced graphene oxide with enhanced catalytic activity and stability for methanol oxidation in alkaline media.
The PtSb/C catalyzed highly selective transformation of glycerol to dihydroxyacetone and H2 was achieved by controlling the applied electrode potential without using oxidants via an electrocatalytic reactor system in acidic media.
A hybrid composite system of MnCo2 O4 nanowires (MCO NWs) anchored on reduced graphene oxide (RGO) nanosheets was prepared as the bifunctional catalyst of a Li-O2 battery cathode. The catalysts can be obtained from the hybridization of one-dimensional MCO NWs and two-dimensional RGO nanosheets. As O2 -cathode catalysts for Li-O2 cells, the MCO@RGO composites showed a high initial discharge capacity (ca. 11092.1 mAh gcarbon (-1) ) with a high rate performance. The Li-O2 cells could run for more than 35 cycles with high reversibility under a limited specific capacity of 1000 mAh gcarbon (-1) with a low potential polarization of 1.36 V, as compared with those of pure Ketjenblack and MCO NWs. The high cycling stability, low potential polarization, and rate capability suggest that the MCO@RGO composites prepared here are promising catalyst candidates for highly reversible Li-O2 battery cathodes.
A schematic of selective electrochemical CO2 conversion to multicarbon alcohols on N-doped porous carbon-supported Cu catalysts via a two-site mechanism is shown.
A highly efficient multidirectional N-doped porous carbon network with plenty of graphitic N-species has been explored as cathode catalysts in fuel cells.
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