Herein, we report a facile, efficient, and practical
protocol that
enables the preparation of aryl xanthates and aryl dithiocarbamates
from functionalized dibenzothiophenium salts via a photoactivated
electron donor–acceptor complex. This mild, metal-free method
is operationally simple and has a broad substrate scope and potential
utility for late-stage functionalization of natural products and pharmaceuticals.
Finally, this method also has redefined the substrate scope and reaction
pathway for the Leuckart thiophenol reaction.
Herein, a new example of relay catalysis, using a combination of Mn2(CO)10 and an iridium-based photocatalyst, is reported. In our relay catalytic reaction, the Mn catalyst and iridium-based photocatalyst catalyze...
Migration of a remote aryl group is a state-of-the-art strategy for difunctionalization of alkenes strategy. Herein, we report a method for visible-light-induced sulfonylarylation reactions of unactivated alkenes via 1,4-(hetero)aryl migration...
Direct functionalization of C(sp3)–H bonds is an effective, straightforward method for accessing a diverse array of heteroarene derivatives. However, its wide application is limited by the need for to use...
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