Vaterite mesocrystals with a hexagonal prism structure were successfully achieved in the presence of sodium citrate (SC) and sodium dodecyl benzenesulfonate (SDBS) by use of a gas-diffusion method at room temperature. X-ray powder diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), transmission electron microscopy (TEM), selected area electron diffraction (SAED), thermogravimetric analysis (TGA), nitrogen physisorption analysis, and fieldemission scanning electron microscopy (FESEM) equipped with energy-dispersive X-ray (EDX) were used to characterize the hexagonal prisms. XRD and FESEM results reveal that the superstructures are composed of hundreds of well-stacked nanoflakes, which construct the laminated hexagonal prism of vaterite. TEM and SAED analyses show that the hexagonal prism has the same crystallographic symmetry as single-crystal vaterite, confirming that the hexagonal prismatic architectures are orientationally aligned mesocrystals of vatreite. However, no hexagonal prism structures can be produced only with SC or SDBS, indicating that the cooperation of SC and SDBS is indispensable to the formation of hexagonal prismatic vaterite mesocrystals. The hexagonal prism mesocrystals of vaterite exhibit remarkable similarity to the nacreous layers of vaterite in freshwater cultured pearls from mussels and the columns/lamellae of vaterite in bivalve in architectures. Therefore, the current study on vaterite mesocrystals will be helpful for us to mimic and learn from nature and may provide another pathway toward full insight into biomineralization mechanism.
[1] Nominally anhydrous clinopyroxene (cpx), orthopyroxene (opx), and plagioclase (pl) from 10 lower crustal granulite (two-pyroxene granulite and hypersthene granulite) xenoliths in Cenozoic basalts from the Nushan volcano, eastern China, have been analyzed for their hydrogen content by microscopic Fourier transform infrared spectroscopy (Micro-FTIR). The results demonstrate that hydrogen was incorporated in all these minerals in the manner of OH and that the content (H 2 O weight) is up to 2360 ppm for cpx, 1170 ppm for opx, and 880 ppm for pl. On the basis of the water content of constitutive minerals and their proportions, whole rock water contents of the Nushan granulites were estimated to be 150-950 ppm. Estimated equilibrium temperatures of the Nushan granulites are in the range of 810-892°C, corresponding to the lowermost crust at Nushan (about 25-30 km). Therefore this study provides direct evidence that the lower continental crust, even the lowermost part devoid of hydrous minerals, can contain a certain amount of water in nominally anhydrous minerals.
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