Using a simple hydrothermal procedure, cobalt oxide (Co(3)O(4)) nanowires were in situ synthesized on three-dimensional (3D) graphene foam grown by chemical vapor deposition. The structure and morphology of the resulting 3D graphene/Co(3)O(4) composites were characterized by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, and Raman spectroscopy. The 3D graphene/Co(3)O(4) composite was used as the monolithic free-standing electrode for supercapacitor application and for enzymeless electrochemical detection of glucose. We demonstrate that it is capable of delivering high specific capacitance of ∼1100 F g(-1) at a current density of 10 A g(-1) with excellent cycling stability, and it can detect glucose with a ultrahigh sensitivity of 3.39 mA mM(-1) cm(-2) and a remarkable lower detection limit of <25 nM (S/N = 8.5).

Quantum key distribution (QKD) uses individual light quanta in quantum superposition states to guarantee unconditional communication security between distant parties. However, the distance over which QKD is achievable has been limited to a few hundred kilometres, owing to the channel loss that occurs when using optical fibres or terrestrial free space that exponentially reduces the photon transmission rate. Satellite-based QKD has the potential to help to establish a global-scale quantum network, owing to the negligible photon loss and decoherence experienced in empty space. Here we report the development and launch of a low-Earth-orbit satellite for implementing decoy-state QKD-a form of QKD that uses weak coherent pulses at high channel loss and is secure because photon-number-splitting eavesdropping can be detected. We achieve a kilohertz key rate from the satellite to the ground over a distance of up to 1,200 kilometres. This key rate is around 20 orders of magnitudes greater than that expected using an optical fibre of the same length. The establishment of a reliable and efficient space-to-ground link for quantum-state transmission paves the way to global-scale quantum networks.

Abstract:We perform decoy-state quantum key distribution between a low-Earth-orbit satellite and multiple ground stations located in Xinglong, Nanshan, and Graz, which establish satellite-to-ground secure keys with ~kHz rate per passage of the satellite Micius over a ground station. The satellite thus establishes a secure key between itself and, say, Xinglong, and another key between itself and, say, Graz.Then, upon request from the ground command, Micius acts as a trusted relay. It performs bitwise exclusive OR operations between the two keys and relays the result to one of the ground stations. That way, a secret key is created between China and Europe at locations separated by 7600 km on Earth. These keys are then used for intercontinental quantum-secured communication. This was on the one hand the transmission of images in a one-time pad configuration from China to Austria as well as from Austria to China. Also, a videoconference was performed between the Austrian Academy of Sciences and the Chinese Academy of Sciences, which also included a 280 km optical ground connection between Xinglong and Beijing. Our work points towards an efficient solution for an ultralong-distance global quantum network, laying the groundwork for a future quantum internet.With the growth of internet use and electronic commerce, a secure global network for data protection is necessary. A drawback of traditional public key cryptography is that it is not possible to guarantee it is information theoretically secure. It has been witnessed in history that every advance of encryption has been defeated by advances in hacking. In particular, with the advent of Shor's factoring algorithm [1], most of the currently used cryptographic infrastructure will be defeated by quantum computers.On the contrary, quantum key distribution (QKD) [2] offers unconditional security ensured by the law of physics. QKD uses the fundamental unit of light, single photons, encoded in quantum superposition states which are sent to a distant location. By proper encoding and decoding, two distant parties share strings of random bits called secret keys. However, due to photon loss in the channel, the secure QKD distance by direct transmission of the single photons in optical fibers or terrestrial free space was hitherto limited to a few hundred kilometers [3][4][5][6][7]. Unlike classical bits, the quantum signal in the QKD cannot be noiselessly amplified owing to the quantum no-cloning theorem [8], already contained at the core of Wiesner's proposal of uncopiable quantum money [9], where the security of the QKD is rooted.The main challenge for a practical QKD is to extend the communication range to long distances, ultimately on a global scale. A promising solution to this problem is exploiting satellite and space-based links [10,11]. That way, one can conveniently connect two remote points on Earth with greatly reduced channel loss because most of the photons' propagation path is in empty space with negligible loss and decoherence. In this work, QKD is performed in a ...

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