Clay-based nanomaterials, especially 2:1 aluminosilicates such as vermiculite, biotite, and illite, have demonstrated great potential in various fields. However, their characteristic sandwiched structures and the lack of effective methods to exfoliate two-dimensional (2D) functional core layers (FCLs) greatly limit their future applications. Herein, we present a universal wet-chemical exfoliation method based on alkali etching that can intelligently “capture” the ultrathin and biocompatible FCLs (MgO and Fe2O3) sandwiched between two identical tetrahedral layers (SiO2 and Al2O3) from vermiculite. Without the sandwich structures that shielded their active sites, the obtained FCL nanosheets (NSs) exhibit a tunable and appropriate electron band structure (with the bandgap decreased from 2.0 eV to 1.4 eV), a conductive band that increased from −0.4 eV to −0.6 eV, and excellent light response characteristics. The great properties of 2D FCL NSs endow them with exciting potential in diverse applications including energy, photocatalysis, and biomedical engineering. This study specifically highlights their application in cancer theranostics as an example, potentially serving as a prelude to future extensive studies of 2D FCL NSs.
Segmented metal−metal heterostructure nanorods/nanowires are very promising for development in photoelectric devices, wearable electronics, biomedicine, and energy storage due to unique surface and interface and adjustable electronic and optical properties. Regretfully, most of the segmented heterojunctions are presently synthesized in organic solvent, and its electronic dynamics is still rarely studied and poorly understood. Here, we reported a pressure-assisted one-step aqueous-phase strategy to successfully synthesize segmented Ag−Au−Ag heterojunction nanorods (HJNRs), the aspect ratios and heterojunction contents of which can be well controlled by varying pressure value. The heterojunction-induced femtosecond-to-nanosecond dynamics in 1D direction of the Ag−Au− Ag HJNRs were for the first time acquired and presented a unique regularity tendency (e.g., electron−phonon scattering time). The unprecedented aqueous-phase strategy opens up horizons of synthesis of other segmented metal−metal HJNRs, and the fascinating Ag−Au−Ag HJNRs are hopeful for the development of a new class devices in photothermal and photoelectronic fields.
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