Performance of green treatment systems such as adsorption to treat textile effluents often suffers lack of longevity and efficiency due to the presence of complex compounds of varying reactivity. There is scope for improving the operational efficiency of such processes using real-time monitoring systems. The present study aims to evaluate the performance of an activated biosorbent prepared from the leaves of Acalypha indica for treating textile industry effluent by simulating process control with real-time monitoring. Batch experiments were performed with synthetic and real-time dye effluents to identify the optimum conditions (pH = 3.0, dosage = 1.0 g/L; time = 1 h) for the highest adsorption capacity (6 mg g−1 and 2 mg g−1). The evaluation of physical parameters suggested best fit for Freundlich isotherm model and pseudo-second order kinetic model. The LabVIEW-based simulation control system enabled close monitoring of pH and temperature during the process. Based on the inputs, an alteration of initial pH has resulted in substantial reduction in COD (73.91%), turbidity (52.43%) and TDS (19.43%). The average incremental increase was highest for COD (45.80 ± 0.06%) compared to TDS (10.13 ± 0.06%) and turbidity (−1.74 ± 0.03%) for varying dosage (3 g–11 g). The proposed framework for incorporating process control-based monitoring system can help achieving better performance.
This study is focused on the application of activated carbon nanoadsorbent derived from Ocimum basilicum Linn (sweet basil) leaves for the removal of methyl orange dye from an aqueous solution. The Ocimum basilicum Linn leaves are dried, powdered, cured with H2SO4, and thermally treated to form an activated carbon biosorbent. Sorbent characterization studies like scanning electron microscope (SEM) and Fourier transform infrared (FTIR) spectroscopy have revealed the adsorption of the methyl orange dye from their aqueous solution in the batch mode process. The biosorbent has shown a maximum adsorption capacity of 1.54 mg g−1 at 10 mg l−1 concentration, 1.2 g sorbent dosage, pH of 3, contact time of 180 min, and pHpzc at 3.9. Experimental results are analyzed using equilibrium models and it is found that the Langmuir isotherm model and kinetic model fit well and also the results have corresponded well with pseudo-first order. The intraparticle diffusion (IPD) mechanism has shown that pore diffusion occurs at a slower rate. The Elovich model has displayed that adsorption is affected by film diffusion. From the statistical optimization studies, it is demonstrated that Box–Behnken model can correlate the good agreement between experimental and predicted values. The highest adsorption capacity for the nanoadsorbent was found using quadrate models and optimizing the variables at a time of 237 min, initial dye concentration of 5.31 mg l−1, adsorbent dose of 1.22 g, and pH of 4.23.
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