This study reports the synthesis of morphology-controlled BaTiO(3) nanostructures such as spherical, cube-shaped and rod-shaped BaTiO(3) using a molten-salt synthesis method. This method synthesized products from a reaction of BaO/BaCO(3) and TiO(2) with a eutectic mixture of NaCl-KCl flux at 700 degrees C for 1 h. The experiment used powder X-ray diffraction, field emission scanning electron microscopy, and transmission electron microscopy to investigate the structure and morphology of the products. Moreover, the current work also provides a proposed synthetic mechanism of BaTiO(3) in the molten salt to illustrate the in situ transformation mechanism of BaTiO(3) nanostructures in the reaction. The results of the study revealed that the initial shape of the titania and the dissolution rate of the initial precursors critically determine the shapes of the final products.

Under a 980 nm laser pumping, quenching of green upconversion (UC) emission accompanied with enhancement of red UC emission observed was dominated by the energy back-transfer (EBT) process in Er(3+) and Yb(3+) co-doped PbTiO(3), BaTiO(3), and SrTiO(3) polycrystalline powders. The efficiency of the EBT process depends not only on Yb(3+) concentration but also on level match of the doped Er(3+) and Yb(3+) ions caused by the crystal fields with different symmetries. Our UC emission spectra and X-ray diffraction confirm that the centrosymmetric crystal field arising from reducing tetragonality causes level match of transition (4)S3/2-->I13/2 of Er(3+) and (2)F7/2-->(2)F5/2 of Yb(3+). This level match is responsible for enhancing red UC emission.

By applying a single-tetragonal-phase model to refine the crystal structure and the coupled-phonon model to analyze transverse optical (TO) modes of BaTiO 3 nanocrystals, we found, upon decreasing the particle size from 140 to 30 nm, that the tetragonality of BaTiO 3 nanocrystallites is reduced accompanied by expanding unit-cell volume, which is the dominant mechanism for reducing giant LO-TO splitting in the BaTiO 3 system. The weakening coupling of two low-frequency modes among three A 1 (TO) phonons leads to changing the lowest one from a spectral dip to a peak, whereas the increasing coupling strength between two high-frequency modes repels them farther so that there is less reduction in spectral separation.

Diaporthe species can infect forest trees, ornamentals, and crops, causing root and fruit rots, stem cankers, leaf spots, etc. (Yang et al. 2018). In February 2021, about 10-20% of jasmine plants showing stem canker, foot rot, and wilting were observed in Changhua (24°01'57.7"N 120°34'54.7"E), Taiwan. The diseased plants initially showed chlorosis, leaf drop, and dieback. Sunken lesions were observed on the infected stem and kept expanding gradually. Eventually, plants wilted and black spots formed on the lesions. The margin of healthy and infected tissues of six samples were cut into 4 pieces, disinfected with 10% NaOCl for 30 seconds, rinsed twice in sterilized distilled water for 1 minute, and cultured on water agar at 28℃ under 12 h light / 12 h dark cycle. Hyphae grown out from isolated tissues were sub-cultured on potato dextrose agar (PDA). All tissues grown out of fungi showed similar colony morphology. Two hyphal tips from different tissues were isolated as representatives and deposited in Bioresource Collection and Research Center, Hsinchu, Taiwan, under BCRC numbers FU31566 and FU31567. The colonies on PDA were white to pale gray and produced black pycnidial conidiomata. The two-week-old conidiomata scattered or aggregated in small groups, exuded cream to pale yellow conidial droplets, 0.3-1.1 mm (n=50). The α-conidia were one-celled, hyaline, ovoid to cylindrical with one or two droplets, 3.8-6.3 × 2.5-3.8 μm (n=50). β-conidia were absent. The internal transcribed spacer (ITS), translational elongation factor subunit 1-α (EF1α), and β-tubulin of the two isolates were amplified using primer pairs ITS1/ITS4 (White et al. 1990), EF1-728F/EF1-986R (Carbone and Kohn 1999), and Bt2a/Bt2b (Glass and Donaldson, 1995), respectively. The ITS (MZ389113, MZ389114), EF1α (MZ419338, MZ419339), and β-tubulin (MZ408893, MZ408894) sequences of two isolates showed 98.55-98.56% (KR936130), 98.82% (KR936133), and 99.11-99.33% (KR936132) match to those of Diaporthe tulliensis R.G. Shivas, Vawdery & Y.P. Tan ex-type isolate BRIP 62248a (Dissanayake et al. 2017), respectively. Based on the morphological and molecular characters, this fungus is identified as D. tulliensis. To confirm the pathogenicity, the needle-wounded stem bases of eight-month-old cutting jasmine seedlings were inoculated with BCRC FU31566 by two PDA disks with actively grown fungal edges or conidial suspension at the concentration of approximately 2 × 105 conidia/ml. Each method inoculated five seedlings, performed in the greenhouse at 25 ± 2°C. Non-inoculated plants served as control. Two weeks after inoculation, three plants inoculated with PDA disks of the fungal culture showed wilting, and conidiomata formed on the stem base. The same symptoms were observed in one plant inoculated with the conidial suspension 3 weeks after inoculation. By contrast, the controls remained symptomless. Koch’s postulates were completed by re-isolating the fungus from the inoculated plant. The re-isolated pathogen showed similar morphology and molecular characteristics to the original. D. tulliensis has been reported to cause cocoa rotted stem in Australia, kiwifruit stem canker in China, and Boston ivy leaf spot in Taiwan (Crous et al. 2015; Bai et al. 2017; Huang et al. 2021; Farr and Rossman 2021). To our knowledge, this is the first report of stem canker on jasmine associated with D. tulliensis in Taiwan. Furthermore, this is the first record of jasmine as a host of D. tulliensis worldwide.

We show the destruction of a displacement of Ti in the short-range structure by observing the disappearance of emission and Raman signals when the Er 3+ concentration exceeds 7 mol% in sol-gel-derived Pb 0.8 La 0.2 TiO 3 polycrystalline films. It is believed that there always exists disorder due to displacement of B ions in the skeleton of BO 6 in perovskite ABO 3 materials. This disorder due to the displacement of Ti ions breaks the center of symmetry to activate emission of rare-earth ions such as Er 3+ and Raman modes of perovskites. We found that the breaking of symmetry can be diminished by introducing more Er 3+ ions.