The design and fabrication of three-dimensional multifunctional architectures from the appropriate nanoscale building blocks, including the strategic use of void space and deliberate disorder as design components, permits a re-examination of devices that produce or store energy as discussed in this critical review. The appropriate electronic, ionic, and electrochemical requirements for such devices may now be assembled into nanoarchitectures on the bench-top through the synthesis of low density, ultraporous nanoarchitectures that meld high surface area for heterogeneous reactions with a continuous, porous network for rapid molecular flux. Such nanoarchitectures amplify the nature of electrified interfaces and challenge the standard ways in which electrochemically active materials are both understood and used for energy storage. An architectural viewpoint provides a powerful metaphor to guide chemists and materials scientists in the design of energy-storing nanoarchitectures that depart from the hegemony of periodicity and order with the promise--and demonstration--of even higher performance (265 references).
This manuscript describes the stepwise, ligand-directed assembly, characterization, and prospective applications of three-dimensional Au and Ag nanoparticle, multlilayered films. Films were prepared by successive treatments of a Au nanoparticle monolayer with a bifunctional cross-linker and colloidal Au or Ag solutions. Changes in film electrical and optical properties are reported for a series of bifunctional cross-linkers of varying molecular lengths. Interestingly, these films exhibit Beer's law behavior despite the presence of strong interparticle optical coupling. Multilayer films with greater than six exposures to 2-mercaptoethylamine and Au colloid were highly conductive and resembled bulk Au in appearance. In contrast, films of similar particle coverage generated using a longer cross-linker (1,6-hexanedithiol) exhibited higher transmission in the near-infrared region and exhibited a reduced conductivity. Measurement of the multilayer morphology with atomic force microscopy , electrostatic force microscopy, and field emission scanning electron microscopy revealed a porous, discontinuous morphology composed of large, continuous regions of aggregated nanoparticles. This, in turn, results in a surface roughness contribution to surface plasmon scattering and surface-enhanced Raman scattering observed for Au, Au/Ag, and Ag colloid multilayers. Particulate multilayer films made using horseradish peroxidase as a cross-linker remained enzymatically active, even beneath three layers of colloidal Au. Multilayers could also be prepared on surfaces patterned by microcontact printing. These data show how Au colloid multilayers grown in solution are a viable alternative to evaporated metal films for a number of applications.
The preparation, characterization, and electrochemical properties of two types of conductive Au films are described. Both films are made entirely by wet chemical procedures. In the first, successive treatment of a Au colloid monolayer/glass substrate with (i) 2-mercaptoethylamine and (ii) colloidal Au in solution leads to systematic buildup of a Au colloid multilayer. After seven to eight layers of Au nanoparticles have been deposited, the multilayers become conductive. Cyclic voltammograms of several different redox couples show that the peak-to-peak separation decreases as the number of layers increases. In the second type of film, a solution of hydroxylamine and Au3+ are used to selectively enlarge the size of a preimmobilized colloidal Au monolayer. Once the particles coalesce, the resulting film can be used to generate voltammograms with narrow peak separations. The ability to form conductive Au films using entirely wet-chemical steps may be valuable for fabrication of electrodes with complex shapes.
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