The quality of interfaces and surfaces is crucial for the performance of nanoscale devices. A pertinent example is the close tie between current progress in gate-tunable and topological superconductivity using semiconductor/superconductor electronic devices and the hard proximity-induced superconducting gap obtained from epitaxial indium arsenide/aluminium heterostructures. Fabrication of devices requires selective etch processes; these only exist for InAs/Al hybrids, which precludes the use of other, potentially better material combinations in functional devices. We present a crystal growth platform based on three-dimensional structuring of growth substrates for synthesising semiconductor nanowires with in-situ patterned superconductor shells, which enables independent choice of material by eliminating etching. We realise and characterise all the most frequently used architectures in superconducting hybrid devices, finding increased yield and electrostatic stability compared to etched devices, along with evidence of ballistic superconductivity. In addition to aluminium, we present hybrid devices based on tantalum, niobium and vanadium.One dimensional semiconductor (SE) nanowires (NWs) proximity coupled to superconductors (SU) have attracted considerable attention from the condensed matter community since the prediction 1,2 and observation of Majorana zero-modes 3-5 , which have been proposed as a basis for topologically protected quantum information processors 6,7 . To ensure topological protection, methods for growing disorder-free 'hard-gap' SE/SU epitaxial hybrids were developed 8-10 . These materials utilise bottom-up crystal growth of InAs nanowires with uniform epitaxial aluminium coatings, an approach which has been extended to high mobility two-dimensional systems 11,12 and selective area grown networks 13,14 . The success of epitaxial InAs/Al hybrids lies in the ability to realise important device classes such as normal metal spectroscopic devices, 5,9,11,12 Josephson Junctions 15-18 for gate-controlled transmon qubits 19,20 , and superconducting Majorana islands 21-23 , using top-down processing to selectively remove the Al. A limitation of this method is that relying on post-process etching inherently limits materials choice. For instance, despite strong incentives to utilise technologically important superconductors such as Nb 24 and NbTiN 25 -which exhibit higher transition temperatures, critical magnetic fields and superconducting energy gaps -selectively removing Nb from InAs remains an unsolved problem. Similarly, InSb is an attractive semiconductor due to its high mobility, g-factor and strong spin-orbit coupling 25-28 . Yet, selectively removing even aluminum from InSb without damage is impossible with known methods. Thus, most potential improvements in epitaxial SE/SU technology are predicated on developing a materials-independent method for device fabrication. An attractive approach to eliminate etching is to employ an in-situ 'shadow approach' to mask specific segments along the NW from supe...

The combination of strong spin-orbit coupling, large g-factors, and the coupling to a superconductor can be used to create a topologically protected state in a semiconductor nanowire. Here we report on growth and characterization of hybrid epitaxial InAsSb/Al nanowires, with varying composition and crystal structure. We find the strongest spin-orbit interaction at intermediate compositions in zincblende InAs1−xSbx nanowires, exceeding that of both InAs and InSb materials, confirming recent theoretical studies [1]. We show that the epitaxial InAsSb/Al interfaces allows for a hard induced superconducting gap and 2e transport in Coulomb charging experiments, similar to experiments on InAs/Al and InSb/Al materials, and find measurements consistent with topological phase transitions at low magnetic fields due to large effective g-factors. Finally we present a method to grow pure wurtzite InAsSb nanowires which are predicted to exhibit even stronger spin-orbit coupling than the zincblende structure.

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Nanowires can serve as flexible substrates for hybrid epitaxial growth on selected facets, allowing for design of heterostructures with complex material combinations and geometries. In this work we report on hybrid epitaxy of semiconductor -ferromagnetic insulator -superconductor (InAs/EuS/Al) nanowire heterostructures. We study the crystal growth and complex epitaxial matching of wurtzite InAs / rock-salt EuS interfaces as well as rock-salt EuS / face-centered cubic Al interfaces. Because of the magnetic anisotropy originating from the nanowire shape, the magnetic structure of the EuS phase are easily tuned into single magnetic domains. This effect efficiently ejects the stray field lines along the nanowires. With tunnel spectroscopy measurements of the density of states, we show the material has a hard induced superconducting gap, and magnetic hysteretic evolution which indicates that the magnetic exchange fields are not negligible. These hybrid nanowires fulfil key material requirements for serving as a platform for spin-based quantum applications, such as scalable topological quantum computing.

Epitaxially connected nanowires allow for the design of electron transport experiments and applications beyond the standard two terminal device geometries. In this Letter, we present growth methods of three distinct types of wurtzite structured InAs nanocrosses via the vapor-liquid-solid mechanism. Two methods use conventional wurtzite nanowire arrays as a 6-fold hexagonal basis for growing single crystal wurtzite nanocrosses. A third method uses the 2-fold cubic symmetry of (100) substrates to form well-defined coherent inclusions of zinc blende in the center of the nanocrosses. We show that all three types of nanocrosses can be transferred undamaged to arbitrary substrates, which allows for structural, compositional, and electrical characterization. We further demonstrate the potential for synthesis of as-grown nanowire networks and for using nanowires as shadow masks for in situ fabricated junctions in radial nanowire heterostructures.