No abstract

Melt size‐dependent physical property variation is examined in a multicomponent GeSe2‐As2Se3‐PbSe chalcogenide glass developed for gradient refractive index applications. The impact of melting conditions on small (40 g) prototype laboratory‐scale melts extended to commercially‐relevant melt sizes (1.325 kg) have been studied and the role of thermal history variation on physical and optical property evolution in parent glass, the glass’ crystallization behavior and postheat‐treated glass ceramics, is quantified. As‐melted glass morphology, optical homogeneity and heat treatment‐induced microstructure following a fixed, two‐step nucleation and growth protocol exhibit marked variation with melt size. These attributes are shown to impact crystallization behavior (growth rates, resulting crystalline phase formation) and induced effective refractive index change, neff, in the resulting optical nanocomposite. The magnitude of these changes is discussed based on thermal history related melt conditions.

No abstract

Beginning with a 19BaF2−27ZnF2−27YbF3−27ThF4 (mol%) base glass, compositional modifications were made to improve optical properties and glass‐forming ability. Replacement of YbF3 by LuF3 removed a strong near‐ir electronic absorption band, and small additions of LiF and NaF improved glass quality. The multicomponent BaF2/ThF4 glasses had higher refractive indices and lower expansion coefficients than fluorozirconate and fluorohafnate glasses. In the 6 to 10 μm region, these materials exhibit absorption coefficients an order of magnitude lower than those reported for other heavy‐metal fluoride glasses.