Single doping and co-doping of N and Ag on TiO2 were successfully prepared by using an in-situ solvothermal method and their structural properties and chemical compositions were characterized. The results indicated that all photocatalysts displayed in TiO2 anatase crystal phase, and a small mesoporous structure was observed in the doped materials. The main roles of N and Ag on the property and photocatalytic activity of TiO2 were different. The N doping has significantly enhanced homogenous surface morphology and specific surface area of the photocatalyst. While Ag doping was narrowing the band gap energy, extending light absorption toward a visible region by surface plasmon resonance as well as delaying the recombination rate of electron and hole of TiO2. The existence of N in TiO2 lattice was observed in two structural linkages such as substitutional nitrogen (Ti-O-N) and interstitial nitrogen (O-Ti-N). Silver species could be in the form of Ag0 and Ag2O. The photocatalytic performance of the photocatalysts coated on stainless steel mesh was investigated by the degradation of aqueous MB and gas phase NH3 under visible LED light illumination for three recycling runs. The highest photocatalytic activity and recyclability were reached in 5% N/Ag-TiO2 showing the efficiency of 98.82% for methylene blue (MB) dye degradation and 37.5% for NH3 removal in 6 h, which was 2.7 and 4.3 times, respectively. This is greater than that of pure TiO2. This was due to the synergistic effect of N and Ag doping.

Mesoporous molecular sieve MCM-41 was synthesized from rice husk and rice husk ash, called RH-MCM-41 and RHA-MCM-41. The sol-gel mixtures were prepared with molar composition of 1.0 SiO 2 : 1.1 NaOH: 0.13 CTAB: 0.12 H 2 O. After calcination, the polarity of MCM-41 still remained on its surface due to the existence of some silanol groups. In this study, both RH-MCM-41 and RHA-MCM-41 were silylated with two different functional silanes trimethylchlorosilane (TMCS) and phenyldimethylchlorosilane (PDMS) in order to reduce the surface polarity. The efficiency of silylation was determined based on the amount of moisture adsorbed using thermogravimetric analysis (TGA). The structure of silylating agents and silica templates were found to be important parameters affecting the hydrophobic property of the MCM-41 surface. The post-grafting silylation with aliphatic silane can decrease the surface polarity better than that with aromatic silane, probably due to less sterric hindrance effect. Thus, the surface hydrophobicity of MCM-41 can be improved by the silylation of small molecular silane on RH-MCM-41. r

Optimum thermal comfort and good indoor air quality (IAQ) is important for occupants. In tropical region offices, an air conditioner is indispensable due to extreme high temperatures. However, the poor ventilation causes health issues. Therefore, the purpose of this study was to propose an improving IAQ method with low energy consumption. Temperature, relative humidity, and CO2 and CO concentration were monitored in a poorly ventilated office for one year to observe seasonal variation. The results showed that the maximum CO2 concentration was above the recommended level for comfort. Simple ventilated practices and placing a number of Sansevieria trifasciata (S. trifasciata) plants were applied to improve the IAQ with the focus on decreasing CO2 concentration as well as achieving energy saving. Reductions of 19.9%, 22.5%, and 58.2% of the CO2 concentration were achieved by ventilation through the door during lunchtime, morning, and full working period, respectively. Placing S. trifasciata in the office could reduce the CO2 concentration by 10.47%–19.29%. A computer simulation was created to observe the efficiency of simple practices to find the optimum conditions. An electricity cost saving of 24.3% was projected for the most feasible option with a consequent reduction in global warming potential, which also resulted in improved IAQ.

Selective adsorbent of benzene, toluene, ethylbenzene, and xylenes (BTEX) was developed based on mesoporous silica materials, RH-MCM-41. It was synthesized from rice husk silica and modified by silane reagents. The silane reagents used in this study were trimethylchlorosilane (TMS), triisopropylchlorosilane (TIPS), and phenyldimethylchlorosilane (PDMS). Physiochemical properties of synthesized materials were characterized by small-angle X-ray diffraction (XRD), Fourier-transformed infrared spectroscopy (FTIR), and surface area analysis. Materials packed in passive air sampler were tested for BTEX uptake capacity. The tests were carried out under an influence of relative humidity (25 to 99 %). Overall, RH-MCM-41 modified by TMS outperformed compared to those modified by other silane agents. The comparative BTEX adsorption on this material and commercial graphitized carbon black was reported.