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The objective of this study was to explore the feasibility and to investigate the mechanism for rapidly monitoring arsenic (As) contamination in agricultural soils with the reflectance spectra of rice plants. Several data pretreatment methods were applied to improve the prediction accuracy. The prediction of soil As contents was achieved by partial least-squares regression (PLSR) using laboratory and field spectra of rice plants, as well as linear regression employing normalized difference spectral index (NDSI) calculated from fild spectra. For laboratory spectra, the optimal PLSR model for predicting soil As contents was achieved using Savitzky-Golay smoothing (SG), first derivative and mean center (MC) (root-mean-square error of prediction (RMSEP)=14.7 mg kg(-1); r=0.64; residual predictive deviation (RPD)=1.31). For field spectra, the optimal PLSR model was also achieved using SG, first derivative and MC (RMSEP=13.7 mg kg(-1); r=0.71; RPD=1.43). In addition, the NDSI with 812 and 782 nm obtained a prediction accuracy with r=0.68, RMSEP=13.7 mg kg(-1), and RPD=1.36. These results indicated that it was feasible to monitor the As contamination in agricultural soils using the reflectance spectra of rice plants. The prediction mechanism might be the relationship between the As contents in soils and the chlorophyll-a/-b contents and cell structure in leaves or canopies of rice plants.

The emergence of big data enables us to evaluate the various human emotions at places from a statistical perspective by applying affective computing. In this study a novel framework for extracting human emotions from large‐scale georeferenced photos at different places is proposed. After the construction of places based on spatial clustering of user‐generated footprints collected from social media websites, online cognitive services are utilized to extract human emotions from facial expressions using state‐of‐the‐art computer vision techniques. Two happiness metrics are defined for measuring the human emotions at different places. To validate the feasibility of the framework, we take 80 tourist attractions around the world as an example and a happiness ranking list of places is generated based on human emotions calculated over 2 million faces detected from greater than 6 million photos. Different kinds of geographical contexts are taken into consideration to find out the relationship between human emotions and environmental factors. Results show that much of the emotional variation at different places can be explained by a few factors such as openness. The research offers insights into integrating human emotions to enrich the understanding of sense of place in geography and in place‐based GIS.

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