4D printing is an emerging additive manufacturing technology that combines the precision of 3D printing with the versatility of smart materials. 4D printed objects can change their shape over time with the application of a stimulus (i.e., heat, light, moisture). Light driven smart materials are attractive because light is wireless, remote, and can induce a rapid shape change. Herein, we present a method for fabricating polymeric bilayer actuators via 3D printing which reversibly change their shape upon exposure to light. The photoactive layer consists of a poly(siloxane) containing pendant azobenzene groups. Two different photoactive polymers were synthesized, and the photomechanical effect displayed by the bilayers was evaluated. These bilayers exhibit rapid actuation with full cycles completed within seconds, and photo generated stresses ranging from 1.03 to 1.70 MPa.
The purpose of this paper is to review the mechanisms of electrohydrodynamic (EHD) phenomenon. From this review, researchers and students can learn principles and development history of EHD. Significant progress has been identified in research and development of EHD high-resolution deposition as a direct additive manufacturing method, and more effort will be driven to this direction soon. An introduction is given about current trend of additive manufacturing and advantages of EHD inkjet printing. Both theoretical models and experiment approaches about the formation of cone, development of cone-jet transition and stability of jet are presented. The formation of a stable cone-jet is the key factor for precision EHD printing which will be discussed. Different scaling laws can be used to predict the diameter of jet and emitted current in different parametrical ranges. The information available in this review builds a bridge between EHD phenomenon and three-dimensional high-resolution inkjet printing.
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