14-Membered metal–ligand ring present in a photosensitive 2D coordination polymer, [Zn2(fum)2(4-phpy)4(H2O)2] (H2fum = fumaric acid and 4-phpy = 4-phenyl pyridine) shows aromatic character as evident by the nucleus-independent chemical shifts (NICS) calculation.

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Water plays pivotal role in many biological and chemical process for living body. Therefore, it is a challenging task to predict the suitable host for confinement of aqua molecules. Here,...

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