Understanding how dissolved trace elements chemically evolve in the Ganga River from source to sink is important to understand subcatchment contributions and chemical variability across space and time but remains poorly constrained. What exists is site-specific data sets that are focused on capturing contamination "hotspots." Here, we present riverine trace element concentrations of 38 targeted locations in the Ganga Basin. Samples in the headwater and the upstream segments of the river were collected during the premonsoon, monsoon, and postmonsoon seasons of 2014, 2015, and 2016, and the downstream samples were collected in 2016. In addition, monthly time-series samples were collected at a downstream site to capture the geochemical variability at a higher temporal-resolution. To evaluate the geogenic contributions, groundwater, rainwater, snow, glacier-ice, and sediment samples were also analyzed. We find that the river chemistry displays a wide spatio-temporal variability. Headwater samples are characterized by high concentrations of trace elements that are primarily controlled by ice meltwater, intense weathering, and interactions with glacial flour and are therefore geogenic in nature. Moreover, high concentrations of trace metals were also observed in a few localized downstream sites. However, such enriched signals are not persistent further downstream as they get diluted by the joining of large tributaries. We show that the dissolved trace element concentrations in the Ganga River are low compared to existing datasets and are comparable to the global average river water composition. We additionally quantified the present-day "baseline" concentration ranges to facilitate future water quality assessment in the Ganga Basin. 1. Introduction Global freshwater availability and quality are constantly changing. A simple explanation for such behavior is climate change and pollution associated with population increase (
The world's large rivers have been intensely studied to better understand the impact of climate change and direct human interventions on river water quality and quantity. Of particular importance is the extent to which industrial, domestic, and agricultural discharges are modifying the dissolved inorganic constituents (major elements, trace elements, nutrients, and heavy metals) of large river systems vis-a-vis water quality. The COVID-19 pandemic lockdown provides a rare opportunity to quantify the impact of restricted anthropogenic activities on the water chemistry resilience of large rivers. By analyzing the daily geochemical record of the Ganga River, we demonstrate that reduced industrial discharge during 51 days of mandated nationwide lockdown decreased the dissolved heavy metal concentrations by a minimum of 50%. In contrast, nitrate and phosphate inputs predominantly derived from agricultural runoff and domestic sewage maintained a chemical status quo as these sources were not impacted by the nationwide confinement or their residence time was longer than the characteristic time of the perturbation. We demonstrate the high resilience of dissolved heavy metals and conclude that industrial wastewater minimization programs will substantially improve heavy metal pollution of the Ganga River in a short time span of a few months.
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