We have investigated the retention forces of liquid drops on rotating, vertical surfaces. We considered two scenarios: in one, a horizontal, centrifugal force pushes the drop toward the surface ("pushed drop" case), and in the other, a horizontal, centrifugal force pulls the drop away from the surface ("pulled drop" case). Both drops slide down as the centrifugal force increases, although one expects that the pushed drop should remain stuck to the surface. Even more surprising, when the centrifugal force is low, the pushed drop moves faster than the pulled drop, but when the centrifugal force is high, the pushed drop moves much slower than the pulled drop. We explain these results in terms of interfacial modulus between the drop and the surface.
Tadmor et al.'s 2009 PRL article shows experiments of pendant drops with ∼30% higher retention forces than their sessile analogues. A recent article (de la Madrid, R. et al. Langmuir 2019, 35, 2871 seemingly explains this result theoretically using a drastically different experimental system that shows a ∼3% higher force that exceeds the scatter in three out of four data points. The differences between the two experimental systems might have allowed the two theories to coexist, but Tadmor's theory, which can explain both, allows an understanding of the solid−liquid interaction, which the newer theory lacks.
In
this paper, we consider drops that are subjected to a gradually
increasing lateral force and follow the stages of the motion of the
drops. We show that the first time a drop slides as a whole is when
the receding edge of the drop is pulled by the advancing edge (the
advancing edge drags the receding edge). The generality of this phenomenon
includes sessile and pendant drops and spans over various chemically
and topographically different cases. Because this observation is true
for both pendant and sessile cases, we exclude hydrostatic pressure
as its reason. Instead, we explain it in terms of the wetting adaptation
and interfacial modulus, that is, the difference in the energies of
the solid interface at the advancing and receding edges. At the receding
edge, a slight motion exposes to the air a recently wetted solid surface
whose molecules had reoriented to the liquid and will take time to
reorient back to the air. This results in a high surface energy at
the solid–air interface which pulls on the triple line, that
is, inhibits the motion of the receding edge. On the other hand, at
the advancing edge, a slight advancement does not change the nature
of the solid interfacial molecules outside the drop, and the advancing
side’s sliding can continue. Moreover, the solid molecules
under the drop at the advancing edge take time to reorient, and hence,
their configuration is not yet adapted for the liquid and therefore
not adapted for retention of the advancing edge. Therefore, in sliding-drop
experiments, the advancing edge moves before the receding one, typically
a few times before the receding edge moves. For the same reason, the
last motion of the receding edge usually happens as a result of the
advancing edge pulling on it.
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