Currently, calcite produced in sediments by microbial-induced carbonate precipitation (MICP) is mainly used as a strengthening binder in sand because sands are porous and have good permeability. Conventional wisdom does not consider MICP to be suitable for use in soft clay because of the clay particles’ small size and its minimal porosity. Because of the clay’s high water content and complex chemical composition, very little research has been done and not much is known about the use of MICP in soft clay for strength enhancement. For this paper, soft clay specimens were prepared by mixing a solution containing Sporosarcina pasteurii bacteria, solutions with different concentrations of nutrient salts, and soft clay. Unconfined compressive strength tests were carried out on these specimens after they had cured for 28 days in a moisture-controlled environment. These laboratory tests were used to study the chemical reactions, the clay’s strength, and other influencing factors. The results are as follows: (1) directly mixing a S. pasteurii solution, nutrient salts, and soft clay considerably improves the uniformity of the spatial distribution of the bacteria and the nutrients in the soft clay. Directly mixing these constituents promotes the formation of calcium carbonate and greatly simplifies soft clay sample preparation. (2) It is feasible to use MICP to increase the strength of soft clay. Compared to control specimens cured under the same conditions but without introduced nutrients and bacteria solution, the unconfined compressive strength of MICP-treated specimens can be increased by as much as 2.42 times to an unconfined compressive strength of 43.31 kPa. The water content in MICP-treated specimens was significantly reduced by the MICP reactions and in one case decreased from 40% to 30.73%. (3) The strength enhancement of microbially solidified soft clay is the result of two processes: urea hydration catalyzed by enzymes consumes water in the clay and the bacterially precipitated calcite forms in the sediment’s pores. (4) The micro-organism-produced calcite in the soft clay increases the calcite abundance from 0% to as much as 3.5%. (5) The MICP-treated strength of soft clay varies with the concentration of the nutrients provided. For the experimental conditions used for this paper, the optimum concentration of the CaCl2·2H2O and CH4N2O nutrients is 0.5 mol/L.
In this paper, three different rock-soil mixtures were reconstituted in laboratory, which were designed to mimic the proportions of coarse and fine particles in the high fill used at the airport construction sites. The shear strength of the reconstituted mixtures was determined by both large-scale direct shear tests (DSTs) with different plate opening sizes and triaxial compression tests. By comparing the test results, the most appropriate plate opening size for DSTs on coarse gap-graded rock-soil mixtures is discussed. The test results indicate that the opening size has a significant effect on the measured shear strength of gap-graded rock-soil mixtures. For DSTs under the same normal stress, the peak strength decreases with increasing plate opening size. For the gap-graded mixture with a small proportion of coarse particles, a plate opening size of one-third to one-quarter of the maximum particle size (dmax) is suitable. With a higher coarse particle content, the opening size should be increased appropriately. If the percentage of gravels (5.0 mm < d < 20.0 mm) is more than 47%, a plate opening size of slightly greater or less than one-half dmax is more appropriate.
The excessive fluorine content in ash-sluicing water has become one of the main environmental pollution problems in the thermal power generation industry. This study selected 5 representative soil types and used fluoride ions (F-) as the pollution control factor. The experimental
results showed that the isotherms of the F- solutions prepared by deionized water (adsorbed by Jianbi clay and Fengrun sandy soil) and ash-sluicing water all conformed to the Langmuir isothermal adsorption equation. In terms of the F- solution prepared with ash-sluicing
water, the adsorption isotherm of Tianshengqiao red clay conformed to the Langmuir isothermal adsorption equation; the adsorption isotherms of Beijing silty soil and Fen River loess conformed to the Henry isothermal adsorption equation. In terms of the maximum adsorption capacity, Tianshengqiao
red clay > Jianbi clay > Beijing silty soil ? Fen River loess > Fengrun sandy soil. Through the experiments, we also found that the adsorption capacity decreased with increasing pH, and the pH buffering effects of the 5 soils, from high to low, were Tianshengqiao red clay > Jianbi
clay > Beijing silty soil > Fen River loess > Fengrun sandy soil.
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