The structures and
phase transitions of [NH
3
(CH
2
)
n
NH
3
]MnCl
4
(
n
= 2, 3,
and 4) crystals were confirmed through
X-ray diffraction and differential scanning calorimetry (DSC) experiments.
Thermodynamic properties, ferroelastic properties, and molecular dynamics
of three crystals were studied as a function of the number (
n
) of CH
2
groups in the alkylene chains. The
loss in molecular weight due to a decrease in
n
marked
the onset of the partial thermal decomposition. The thermal decomposition
temperature,
T
d
, increased with increasing
length of the CH
2
chain. While the ferroelastic twin domain
walls for
n
= 2 and 4 were in the same direction
at all temperatures, the domain walls for
n
= 3 were
rotated by 45°, and the direction of extinction in phase II was
rotated by 45° with respect to phases I and III. The
1
H and
13
C MAS NMR spectra of the three crystals were recorded
as a function of temperature. With increasing length of the CH
2
chain, the
1
H spin relaxation time decreased,
indicating that molecular motions were activated. These results provide
insights into the thermodynamic properties and structural dynamics
of the [NH
3
(CH
2
)
n
NH
3
]MnCl
4
crystals and are expected to facilitate
their potential applications.
The thermal- and mechanical-properties and optical transparency of the copoly(amide imide) films with different BPA monomer contents were investigated.
Although PEI/PAA multilayers are insulators, when used as a p-type buffer layer in organic photodetector, they suppressed the leakage current and also provided a high photocurrent due to the light-assisted tunneling effect.
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