Polymer composite films containing fillers comprising quasi‐1D van der Waals materials, specifically transition metal trichalcogenides with 1D structural motifs that enable their exfoliation into bundles of atomic threads, are reported. These nanostructures are characterized by extremely large aspect ratios of up to ≈106. The polymer composites with low loadings of quasi‐1D TaSe3 fillers (<3 vol%) reveal excellent electromagnetic interference shielding in the X‐band GHz and extremely high frequency sub‐THz frequency ranges, while remaining DC electrically insulating. The unique electromagnetic shielding characteristics of these films are attributed to effective coupling of the electromagnetic waves to the high‐aspect‐ratio electrically conductive TaSe3 atomic‐thread bundles even when the filler concentration is below the electrical percolation threshold. These novel films are promising for high‐frequency communication technologies, which require electromagnetic shielding films that are flexible, lightweight, corrosion resistant, inexpensive, and electrically insulating.
We report on the investigation of thermal transport in noncured silicone composites with graphene fillers of different lateral dimensions. Graphene fillers are comprised of few-layer graphene flakes with lateral sizes in the range from 400 to 1200 nm and the number of atomic planes from 1 to ∼100. The distribution of the lateral dimensions and thicknesses of graphene fillers has been determined via atomic force microscopy statistics. It was found that in the examined range of the lateral dimensions, the thermal conductivity of the composites increases with increasing size of the graphene fillers. The observed difference in thermal properties can be related to the average gray phonon mean free path in graphene, which has been estimated to be around ∼800 nm at room temperature. The thermal contact resistance of composites with graphene fillers of 1200 nm lateral dimensions was also smaller than that of composites with graphene fillers of 400 nm lateral dimensions. The effects of the filler loading fraction and the filler size on the thermal conductivity of the composites were rationalized within the Kanari model. The obtained results are important for the optimization of graphene fillers for applications in thermal interface materials for heat removal from high-power-density electronics.
We report on the room-temperature switching of 1T-TaS2 thin-film charge-density-wave devices, using nanosecond-duration electrical pulsing to construct their time-resolved current-voltage characteristics. The switching action is based upon the nearly-commensurate to incommensurate charge-density-wave phase transition in this material, which has a characteristic temperature of 350 K at thermal equilibrium. For sufficiently short pulses, with rise times in the nanosecond range, self-heating of the devices is suppressed, and their current-voltage characteristics are weakly nonlinear and free of hysteresis. This changes as the pulse duration is increased to ~200 ns, where the current develops pronounced hysteresis that evolves non-monotonically with the pulse duration.By combining the results of our experiments with a numerical analysis of transient heat diffusion in these devices, we clearly reveal the thermal origins of their switching. In spite of this thermal character, our modeling suggests that suitable reduction of the size of these devices should allow their operation at GHz frequencies.
We report on the fabrication and characterization of electronic
devices printed with inks of quasi-one-dimensional (1D) van der Waals
materials. The quasi-1D van der Waals materials are characterized
by 1D motifs in their crystal structure, which allow for their exfoliation
into bundles of atomic chains. The ink was prepared by the liquid-phase
exfoliation of crystals of TiS3 into quasi-1D nanoribbons
dispersed in a mixture of ethanol and ethylene glycol. The temperature-dependent
electrical measurements indicate that the electron transport in the
printed devices is dominated by the electron hopping mechanisms. The
low-frequency electronic noise in the printed devices is of 1/f
γ
-type
with γ ∼ 1 near-room temperature (f is
the frequency). The abrupt changes in the temperature dependence of
the noise spectral density and γ parameter can be indicative
of the phase transition in individual TiS3 nanoribbons
as well as modifications in the hopping transport regime. The obtained
results attest to the potential of quasi-1D van der Waals materials
for applications in printed electronics.
We
report on the preparation of flexible polymer composite films
with aligned metallic fillers composed of atomic chain bundles of
quasi-one-dimensional (1D) van der Waals material, tantalum triselenide
(TaSe3). The material functionality, embedded at the nanoscale
level, is achieved by mimicking the design of an electromagnetic aperture
grid antenna. The processed composites employ chemically exfoliated
TaSe3 nanowires as the grid building blocks incorporated
within the thin film. Filler alignment is achieved using the “blade
coating” method. Measurements conducted in the X-band frequency
range demonstrate that the electromagnetic transmission through such
films can be varied significantly by changing the relative orientations
of the quasi-1D fillers and the polarization of the electromagnetic
wave. We argue that such polarization-sensitive polymer films with
unique quasi-1D metallic fillers are applicable to advanced electromagnetic
interference shielding in future communication systems.
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