Photoelectrochemical (PEC) water splitting offers a sparkling and sustainable strategy for hydrogen generation, and significant research for enhancing the conversion efficiency of electrocatalysts is underway, since a huge number of publications have been reported in this field. Hence, it is urgent to write a comprehensive and updated review in order to highlight the latest progress in the design, fabrication, and modification of electrocatalysts for high-efficiency PEC water splitting. In this review, we describe the basic mechanism of PEC water splitting utilizing electrocatalysts in detail. Further, we highlighted the recent advancements in the design, fabrication, and modification of high-efficiency electrocatalysts for energy conversion. In addition, the catalysts' surface passivation, heterojunction constructions, defect engineering, and photovoltage and photocurrent enhancements are also highlighted.

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Purpose This paper aims to investigate the influence of different post-annealing cooling conditions, i.e. furnace cooling (heat treatment (HT) 1 – slow cooling) and air cooling (HT 2 – fast cooling), on the microstructure and mechanical properties of selective laser melting (SLM) built austenitic 316L stainless steel (SS). Design/methodology/approach Three sets of 316L SS samples were fabricated using a machine standard scanning strategy. Each set consists of three tensile samples and a cubic sample for microstructural investigations. Two sets were subsequently subjected to annealing HT with different cooling conditions, i.e. HT 1 and HT 2, whereas one set was used in the as-built (AB) condition. The standard metallographic techniques of X-ray diffraction, scanning electron microscopy and electron back-scattered diffraction were used to investigate the microstructural variations induced by different cooling conditions. The resultant changes in mechanical properties were also investigated. Findings The phase change of SLM fabricated 316L was observed to be independent of the investigated cooling conditions and all samples consist of austenite phase only. Both HT 1 and HT 2 lead to dissolved characteristic melt pools of SLM. Noticeable increase in grain size of HT 1 and HT 2 samples was also observed. Compared with AB samples, the grain size of HT 1 and HT 2 was increased by 12.5% and 50%, respectively. A decreased hardness and strength, along with an increased ductility was also observed for HT 2 samples compared with HT 1 and AB samples. Originality/value From previous studies, it has been noticed that most investigations on HT of SLM fabricated 316L were mainly focused on the HT temperature or holding time. However, the post-HT cooling rate is also an equally important factor in deciding the microstructure and mechanical properties of heat-treated components. Therefore, this paper investigates the influence of different post-annealing cooling conditions on microstructure and mechanical properties of SLM fabricated 316L components. This study provides a foundation for considering the post-HT cooling rate as an influential parameter that controls the properties of heat-treated SLM components.

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