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Biogenic apatite preserved in 148 samples of conodonts and organophosphatic-shelled brachiopods from Cambrian through Ordovician successions of the Baltoscandian Basin (Baltica Plate) preserves a sensitive record of early Palaeozoic sea-water chemistry interpreted via neodymium isotope ratios. Consistent ε Nd (t) values of −9.6 to −8.3 for Lower to Middle Cambrian samples suggest no significant lateral or temporal variation across the region. Average Upper Cambrian values are −7.2 to −7.7. Sedimentary analysis suggests that the influence of continental weathering from Baltica as a major source of radiogenic Nd was negligible. Ordovician samples show a rise to −5 to −6 in the early Arenig, early-mid Llanvirn and late Caradoc. Sea-water mixing from the southeast Iapetus Ocean was a constant factor throughout Cambrian-Ordovician times. The rise reflects erosion of obducted volcanic arc complexes along the Caledonian margin, and probably also relates to pollution of the Baltica sector of Iapetus from the approaching Avalonia Plate. Patterns of evolutionary biodiversity and palaeobiogeographical linkages support the geochemical signatures in interpreting the tectonic history of the region. Extinction of lingulate brachiopod faunas in the Tremadoc, followed by subsequent recovery and emergence of benthic assemblages typical of the Ordovician Evolutionary Fauna in the Billingen-early Volkhov regional stages coincide with significant changes in geochemical characteristics of water masses across the Baltoscandian basin. The early and mid Ordovician (Arenig to Llandeilo) brachiopod faunas of the North Estonian Confacies Belt are characterized by high endemism and low turnover rates, whereas increased immigration resulted in the extinction of a number of local lineages in the late Llanvirn. From the mid Caradoc to mid Ashgill, when Baltica was drifting on a course to collide eventually with Avalonia and gradually approach Laurentia, brachiopod assemblages were characterized by higher turnover rates. At the same time they gradually became more cosmopolitan and less influenced by the invasion of new faunas.

Sedimentary organic matter deriving from tubes of sabelliditids, vendotaenids, sapropelic films and kerogens was extracted by acid processing from Upper Vendian siliciclastic successions in the East European Platform. Elemental composition obtained by instrumental neutron activation analysis (INAA) displays the increasing cobalt (Co) concentration from 1 ppm at the bottom of Upper Vendian succession to about 800 ppm in the uppermost part near the Precambrian–Cambrian boundary. This distribution is recorded in all studied successions and is not related to resistant minerals that survived acid treatment. The enrichment in Co and other metals in the sedimentary organic matter is inferred to be caused by the bloom of cyanobacterial microbiota, and bonding of metals in decaying sedimentary organic matter during pre-burial bacterial reworking and post-burial early diagenesis in a low energy, stagnant depositional basin during Kotlin times. The positive Ceanom in probable benthic sabelliditids, and the exceptional preservation of sedimentary organic matter from Kotlinian strata, indicate the anaerobic conditions during their sedimentation. Clear correlations between 87Sr/86Sr, δ13C and Co imply the secondary isotopic signatures of Sr and C in sedimentary organic matter deriving from a restricted epicontinental marine basin.