The development of a visible-light-active photocatalyst
for the
removal of organic contaminants from water is of primary importance.
In this work, we have developed a one-pot synthesis method for visible-light-active
aluminum-doped titania (TiO2) with highly efficient sorption
degradation of the fluoroquinolone-based pharmaceutical pollutant
norfloxacin in aqueous solution. Here, we reduced the effective band
gap of TiO2 by in situ doping of aluminum (1 mol %), which
significantly improves the porosity, resulting in a high sorption
capacity (209 mg/g) toward norfloxacin. The doping of aluminum in
TiO2 makes it photocatalytically active in visible light
and overcomes the shortcomings of undoped TiO2 in favor
of the photodegradation process. 1% aluminum-doped TiO2 (AT) nanoflakes achieves 93% norfloxacin removal (of 2 × 10–4 M) in 2 h with almost 5 times higher rate constants
(0.0143 min–1) compared to undoped TiO2 nanoflakes under visible light. Additionally, a high bacterial disinfection
activity of doped samples compared to undoped TiO2 in visible
light (nearly 80%) as well as in the dark (nearly 20%) was also observed
toward both Staphylococcus aureus and Escherichia
coli bacteria. The end product of the degradation process
was analyzed using mass spectroscopy to determine the mechanistic
pathways of the degradation process and the fate of the pollutants.
The reusability of the prepared samples was tested and found to be
active even after several cycles.
Crystalline phases along with the morphology of any semiconducting material are the key factors which govern its photocatalytic properties. Herein, we have prepared a composite of α- and δ-MnO2 with...
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