CZTS is a promising photoabsorber as a photocathode for water reduction to produce hydrogen but its performance is often limited by the presence of a high concentration of defects. Here, substitution of Cd improves the bulk quality of CZTS, resulting in a photocurrent enhancement of 4 mA cm À2 to 17 mA cm À2 at 0 V RHE . This improvement is attributed to the better charge collection, which may be due to the reduction in band tailing or band-edge defects and improved carrier transport properties.

The photodissociation dynamics of tert-C(4)H(9)Br and iso-C(4)H(9)Br has been studied at 234 and 265 nm using two-dimensional velocity map imaging technique. The translational energy and angular distributions have been analyzed for Br, Br(*), and tert-C(4)H(9) radical. The energy distribution of Br atom in the photodissociation of tert-C(4)H(9)Br is found to consist of two Gaussian components. The two components are correlated to two independent reaction paths on the excited potential energy surfaces: (1) the high-energy component from the prompt dissociation along the C-Br stretching mode and (2) the low-energy component from the repulsive mode along the C-Br stretching, coupled with some bending motions. For the energy distribution of Br(*) atom in the photodissociation of tert-C(4)H(9)Br, a third multiphoton dissociative ionization channel is observed at 265 nm in addition to the two energy components corresponding to channels (1) and (2). The energy distributions of Br and Br(*) atoms in the photodissociation of iso-C(4)H(9)Br can be fitted using only one Gaussian function indicating a single formation channel. Relative quantum yields for Br((2)P(32)) at 234 and 265 nm in the photodissociation of tert-C(4)H(9)Br are measured to be 0.76 and 0.65, respectively. For iso-C(4)H(9)Br, the measured value is Phi(234 nm)(Br)=0.81. The contribution of bending modes to Br and Br(*) is much more obvious in the photodissociation of tert-C(4)H(9)Br than in iso-C(4)H(9)Br.

The investigation of gas transport in microfractures of tight/shale reservoirs can provide potential applications in predicting shale gas production rates. In this paper, analytical expressions for flow rate and apparent permeability are derived based on the fractal theory and the superposition of convection and molecular diffusion transfer. The proposed model relates the flow rate and apparent permeability to the microstructural parameters of tight/shale reservoirs, gas properties, the ambient pressure as well as temperature. The model predictions from the present model are compared with existing experimental data sets and are found to be consistent with existing experimental measurements. The effects of microstructural parameters of tight/shale reservoirs on apparent permeability are also investigated. The results show that apparent permeability increases with temperature, the pore area fractal dimension, the porosity as well as the maximum microfracture width and decreases with the tortuosity fractal dimension and the mean pressure.

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