Two photoluminescent polymorphs exhibit different mechanoluminescence activities and mechanochromic behaviors.

An effective strategy for the molecular design of AIE-ML materials is demonstrated based on tetraphenylethene with formyl substituents.

We propose theoretically and demonstrate experimentally a dislocated double-layer metal grating structure, which operates as a unidirectional coupler capable of launching surface plasmon polaritons in a desired direction under normal illumination. The structure consists of a slanted dielectric grating sandwiched between two gold gratings. The upper gold grating has a nonzero lateral relative displacement with respect to the lower one. Numerical simulations show that a grating structure with 7 periods can convert 49% of normally incident light into surface plasmons with a contrast ratio of 78 between the powers of the surface plasmons launched in two opposite directions. We explain the unidirectional coupling phenomenon by the dislocation-induced interference of the diffracted waves from the upper and lower gold gratings. Furthermore, we developed a simple and cost-effective technique to fabricate the structure via tilted two-beam interference lithography and subsequent shadow deposition of gold. The experimental results demonstrate a coupling efficiency of 36% and a contrast ratio of 43. The relatively simple periodic nature of our structure lends itself to large-scale low-cost fabrication and simple theoretical analysis. Also, unlike the previous unidirectional couplers based on aperiodic structures, the design parameters of our unidirectional coupler can be determined analytically. Therefore, this structure can be an important component for surface-plasmon-based nanophotonic circuits by providing an efficient interface between free-space and surface plasmon waves.

Surface-enhanced Raman scattering (SERS) spectroscopy has found a wide range of applications in biomedicine, food safety and environmental monitoring. However, to date, it is difficult for most SERS substrates to provide an extremely sensitive and highly uniform Raman response simultaneously. Here, we developed a sensitive and uniform SERS sensing strategy based on grating-integrated gold nanograsses (GIGNs), which can amplify the SERS signal up to 10-fold compared to the nanograss without grating (namely on the flat substrate) experimentally. Numerical simulation results show that such an improvement of SERS sensitivity arises from the enhanced hotspots relying on the strong coupling between the localized surface plasmon resonances of individual stripe-regulated gold nanorod assemblies and Wood's anomalies in air and dielectric grating. Importantly, these hotspots on the substrate can be flexibly tailored by adjusting the height and periodicity of the loaded grating. The SERS performances of the GIGNs have further been successfully demonstrated with the label-free detection of adenine and cytosine (DNA bases) molecules at the nanomolar level.Moreover, the GIGNs also presented the uniform spot-to-spot and sample-to-sample SERS signals of the analyte molecules (relative standard deviations down to B11% and 13%, respectively). These advantages suggest that our GIGN substrates are of great potential for SERS-related sensing.

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