In the present study, the geochemical characteristics of groundwater and drinking water quality has been studied. 24 groundwater samples were collected and analyzed for pH, electrical conductivity, total dissolved solids, carbonate, bicarbonate, chloride, sulphate, nitrate, calcium, magnesium, sodium, potassium and total hardness. The results were evaluated and compared with WHO and BIS water quality standards. The studied results reveal that the groundwater is fresh to brackish and moderately high to hard in nature. Na and Cl are dominant ions among cations and anions. Chloride, calcium and magnesium ions are within the allowable limit except few samples. According to Gibbs diagram, the predominant samples fall in the rock-water interaction dominance and evaporation dominance field. The piper trilinear diagram shows that groundwater samples are Na-Cl and mixed CaMgCl type. Based on the WQI results majority of the samples are falling under excellent to good category and suitable for drinking water purposes.

The present study was carried out to evaluate the groundwater quality and its suitability for drinking purposes in the urban coastal aquifers of part of south Chennai, Tamil Nadu, India. Twenty-three groundwater samples were collected during March 2012. The minimum and maximum values of pH (6.3-8 on scale), electrical conductivity (620-12,150 lS/cm), total dissolved solids (399.28-7,824.6 mg/l), carbonate (0-30 mg/l), bicarbonate (0.9-58.9 mg/l), chloride (70.9-4,067.89 mg/l), sulphate (17.4-105 mg/l), nitrate (0.4-6.0 mg/l), calcium (30-200 mg/l), magnesium (1.2-164 mg/l), sodium (69-1,490 mg/ l) and potassium (8-340 mg/l) were recorded in the coastal aquifers of Chennai city. The groundwater samples show that the majority of the sampling points clustered on the NaCl and mixed CaMgCl facies of the piper trilinear diagram. In the Gibbs diagram, the majority of the sampling points fall under rock water and evaporation dominance field. Fuzzy membership classification suggests that the majority of the samples fall under good water type followed by excellent water and poor water categories. Groundwater quality index showing the majority of the samples falls under excellent to poor category of water. A positive correlation was observed with Cl-, SO 4 2-, Ca 2? , Na ? , K ? , EC and TDS. The extracted results of the correlation matrix and geochemical analysis suggest that the dominant ions of groundwater (Na ? , Ca 2? , K ? , Cland SO 4 2-) were derived from seawater intrusion and gypsum dissolution process. Nitrate concentration is most significantly derived from anthropogenic sources.

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Groundwater quality assessment has been carried out based on physicochemical parameters (pH, EC, TDS, CO(3), HCO(3), Cl, SO(4), PO(4), NO(2), Ca(+2), Mg(+2), Na(+) and K(+)) and metal concentration in the Rameswaram Island from 25 bore wells. The Langelier Saturation Index of the groundwater shows positive values (63% samples) with a tendency to deposit the CaCO(3) in the majority of water samples. Scatter plot (Ca + Mg/HCO(3)) suggests carbonate weathering process, which is the main contributor of Ca(2+), Mg(2+) and HCO(3) ions to the water. Gibbs diagram suggests rock-water interaction dominance and evaporation dominance which are responsible for the change in the quality of water in the study area. NaCl and mixed CaNaHCO(3) facies are two main hydrogeochemical facies of groundwater. Mathematical calculations and graphical plots of geochemical data reveal that the groundwater of Rameswaram Island is influenced by natural weathering of rocks, anthropogenic activities and seawater intrusion due to over exploitation. Weathering and dissolution of carbonate and gypsum minerals also control the concentration of major ions (Ca(+2), Mg(+2), Na(+) and K(+)) in the groundwater. The nutrient concentration of groundwater is controlled to a large extent by the fertilizers used in agricultural lands and aquaforms. Comparison of geochemical data shows that majority of the groundwater samples are suitable for drinking water and irrigation purposes.

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