Oxide films or inclusions can reduce the continuity and integrity of materials and they always lead to a significant reduction in the mechanical properties of an aluminum alloy. They can greatly reduce the plastic flow behavior of materials, thus affecting the subsequent processing performance. Therefore, an effective ultrasonic assisted preparation technology has been applied to industrial manufacturing of large-scale aluminum alloy ingots (with diameter: Φ = 1250 mm and height: h = 3750 mm). However, the mechanisms of ultrasonic purification on the large-scale ingots are not clear. Therefore, a number of aluminum alloy casting experiments were carried out to produce a conventional hot top semi-continuous ingot (CHTI) and an ultrasonic hot top semi-continuous ingot (UHTI) in this work. The microstructures of CHTI and UHTI were analyzed by optical microscopy (OM) and scanning electron microscopy (SEM). The results indicated that there were some oxide film defects in the CHTI but some finely dispersed inclusion particles were discovered in the UHTI. The X-ray diffraction (XRD) data showed that the component of inclusion was Al2O3. According to the different cavitation effects of the different areas of the molten aluminum, the process of ultrasonic purification was divided into three periods and the mechanisms in each period were separately studied.
Hydrophobic/superhydrophobic materials with intrinsic water repellence are highly desirable in engineering fields including anti-icing in aerocrafts, antidrag and anticorrosion in ships, and antifog and self-cleaning in optical lenses, screen, mirrors, and windows. However, superhydrophobic material should have small surface energy (SE) and a micro/nanosurface structure which can reduce solid-liquid contact significantly. The low SE is generally found in organic materials with inferior mechanical properties that is undesirable in engineering. Intriguingly, previous theoretical calculations have predicted a negative SE for θ-alumina (θ-Al2O3), which inspires us to use it as a superhydrophobic material. Here, we report the experimental evidence of the small/negative SE of θ-Al2O3 and a θ-Al2O3-based superhydrophobic coating prepared by one-step scalable plasma arcing oxidation. The superhydrophobic coating has complete ceramic and desired micro/nanostructure and therefore exhibits excellent aging resistance, wear resistance, corrosion resistance, high-temperature tolerance, and burning resistance. Owing to the rarity of the small/negative SE in inorganic materials, the concept to reduce SE by θ-Al2O3 may foster a blowout to develop robust superhydrophobicity by complete inorganic materials.
The structure and composition of large-scale Al–Cu alloy ingots are inhomogeneous, and the segregation of (especially) elemental Cu negatively affects the uniformity and stability of the subsequent components. In this work, four ultrasonic generators were used to manipulate solidification/microstructures of cylindrical Al–Cu ingots (1250 mm in diameter; 3500 mm in length). The influence of ultrasonic configuration on both solidification microstructures and solute macrosegregation was investigated by changing the position parameters of generators for a fixed power. The results revealed that when the ultrasound is applied close to the center (I) from the 1/2 radius (II), the grain structure of the center undergoes significant refinement, degree of positive segregation in the center can be reduced, segregation index decreased from 0.2 to 0.15, and range of positive segregation in the center decreased from 200 to 150 mm. The segregation of elemental Cu was weakened by the combined effects of the ultrasound on the flow, heat transfer, and grain movement.
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