After many efforts, the core-shell nanostructure of LaOF:Eu3+SiO2 that emits bright red radiation can be fabricated by simple solvothermal application succeeded by heat treatment. The resulted particles from the fabrication process are small in size, able to demonstrate circular form more efficient and prevent stacking. Photoluminescence (PL) emission spectra exhibits intense peaks at 593 nm, 611 nm, 650 nm corresponds to 5D0 -- 7FJ (J = 0, 1 and 2) Eu3+ transitions respectively. The spectral intensity parameters and Eu-O ligand behaviors are estimated by means of Judd-Ofelt (J-O) theory. CIE co-ordinates are found to be (x = 0.63, y = 0.36) which is very close to standard NTSC values (x = 0.67, y = 0.33). CCT value is 3475 K which is less than 5000 K, as a result this phosphor is suitable for warm light emitting diodes. The optimized core-shell SiO2 (coat III)@LaOF:Eu3+ (5 mol%) was used as a fluorescent labeling marker to identity latent fingerprints on both porous and non-porous surfaces. The fingerprints results are highly sensitive, selective and also has no obstruction caused by the back-ground which supports level-I to level-III fingerprint ridge recognition. The experiments outcomes suggest that the enhancements brought by the core-shell NS structure can be further examined to apply in forensic and solid state lightning applications.
Phosphors that offer considerable performance as well as heat consistency has been a high priority of recent studies concerning light-emitting diodes (LED) devices. This study employs the perovskite phosphors BCSOF (short for Ba<sub>1-x</sub>Ca<sub>x</sub>ScO<sub>2</sub>F:0.001Bi3+,0.001K+ with x value from 0 to 0.12 and one chip at 415 nm generating thin green illumination via cation-replacement method. The study examines the aftermath when Ca<sup>2+</sup> replaces Ba<sup>2+</sup> within the crystal formations of BCSOF as well as the luminescent features of the phosphors, detecting a formation of cube-like perovskite within the space group of Pm3m in the employed phosphors. In addition, the study also assesses the development concerning the magnitude of cells as well as the binding extent of Ba/Ca/K/Bi-O. When the inner quantum performance reaches 77.4% in BCSOF, a potent green discharge is manifested, reaching 510 nm when excited by a chip at 415 nm. Greater luminescent performance as well as heat consistency correlating with changes in inner formation were reported. Via the method of replacing cations, it is possible to control spectrum by manipulating the latticework’s surroundings, leading to desirable performance in LED products.
Sr3Al2O5Cl2:Bi3+ (SAlOCl:Bi3+)phosphor for broadband emission was made using a solid-state method. From the extensive spectroscopic analysis and theoretical computation, significant conclusions about the origin of the Bi3+ emission were drawn. For the Sr 3 and Sr 1 sites, respectively, the dipole-quadrupole and quadrupole-quadrupole interactions were responsible for the concentration quenching in SAlOCl:Bi3+. The resulting luminescence mechanism demonstrated that the crystallization of Bi3+ at the two sites is what causes the emission from each site. The warm white light emitting diodes (LED) models were built with a 380-nm ultraviolet (UV) chip, SAlOCl:Bi3+, and two other phosphors. Then, the color rendering indeces (CRI) and the correlated color temperature (CCT) were calculated. Particularly, the CRI values ranged from 84.3 to 86.2 under operating currents of 20–50 mA, respectively. The increasing SAlOCl:Bi3+ dosage also heightened particle density, resulting in higher scattering coefficients. High scattering results in improved color coordination (lower color variance). The CRI and luminous flux are reduced as the phosphor SAlOCl:Bi3+ concentration increases more than owing to color loss and energy loss by backscattering and re-absorption. Thus, it is advisable to consider SAlOCl:Bi3+ carefully before applying in production.
The pomising uses of near infrared (NIR) phosphor converted light emitting diodes (pc-LEDs), including non-destructive testing and biological implementations, are endless. It is still difficult to create wideband and NIR phosphors with sufficient heating steadiness for a variety of uses. The study herein introduces the phosphor Sr3Ga2Ge4O14:Cr3+, its creation procedure through expreiments as well as its influneces on LED devices. The Sr3Ga2Ge4O14:Cr3+ (SGGO:Cr3+) super-wideband NIR phosphor was effectively synthesized in this study with 431 nm stimulation, and a spectrum adjustment 750 nm-900 nm was made in a two-step superwideband radiation having its full width under half maximum (FWHM) changing among 257 and 336 nm. The inner quantum performance (IQP) for SGGO:0.15Cr3+ is 36.67%, and it has an FWHM of 257 nm. At 423 K, the emitting strength was still 76% of ambient temperature. The potential of SGGO:Cr3+ for various uses was eventually demonstrated by the employment of SGGO:0.03Cr3+ as well as SGGO:0.15Cr3+ samples accompanied by blue illumination chips under 430 nm for the task of creating NIR pc-LED gadgets then putting in nighttime sight, human palm puncture, flora lighting. It was shown that SGGO:Cr3+ has a wide range of use possibilities.
Sr3Al2O5Cl2:Bi3+ (SAlOCl:Bi3+)phosphor for broadband emission was made using a solid-state method. From the extensive spectroscopic analysis and theoretical computation, significant conclusions about the origin of the Bi3+ emission were drawn. For the Sr 3 and Sr 1 sites, respectively, the dipole-quadrupole and quadrupole-quadrupole interactions were responsible for the concentration quenching in SAlOCl:Bi3+. The resulting luminescence mechanism demonstrated that the crystallization of Bi3+ at the two sites is what causes the emission from each site. The warm white light emitting diodes (LED) models were built with a 380-nm ultraviolet (UV) chip, SAlOCl:Bi3+, and two other phosphors. Then, the color rendering indeces (CRI) and the correlated color temperature (CCT) were calculated. Particularly, the CRI values ranged from 84.3 to 86.2 under operating currents of 20–50 mA, respectively. The increasing SAlOCl:Bi3+ dosage also heightened particle density, resulting in higher scattering coefficients. High scattering results in improved color coordination (lower color variance). The CRI and luminous flux are reduced as the phosphor SAlOCl:Bi3+ concentration increases more than owing to color loss and energy loss by backscattering and re-absorption. Thus, it is advisable to consider SAlOCl:Bi3+ carefully before applying in production.
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