Illumination of colloid sphere monolayers by circularly polarized beams enables the fabrication of concave patterns composed of circular nanohole miniarrays that can be transferred into convex metal nano-object patterns via a lift-off procedure. Unique spectral and near-field properties are achievable by controlling the geometry of the central nanoring and quadrumer of slightly rotated satellite nanocrescents and by selecting those azimuthal orientations that promote localized plasmon resonances. The spectral and near-field effects of hexagonal patterns composed of uniform gold nanorings and nanocrescents, which can be prepared by transferring masks fabricated by a perpendicularly and obliquely incident single homogeneous circularly polarized beam, were studied to uncover the supported localized plasmonic modes. Artificial rectangular patterns composed of a singlet nanoring and singlet nanocrescent as well as quadrumer of four nanocrescents were investigated to analyze the effect of nano-object interactions and lattice type. It was proven that all nanophotonical phenomena are governed by the azimuthal orientation independent localized resonance on the nanorings and by the C2, C1, and U resonances on the nanocrescents in case of $\bar {E}$ Ē -field direction perpendicular and parallel to their symmetry axes. The interaction between localized surface plasmon resonances on individual nano-objects is weak, whereas scattered photonic modes have a perturbative role at the Rayleigh anomaly only on the larger periodic rectangular pattern of miniarrays. Considerable fluorescence enhancement of dipolar emitters is achievable at spectral locations promoting the C and U resonances on the constituent nano-object.
The use of circularly polarized beams in interferometric illumination of colloid sphere monolayers enables the direct fabrication of rectangular patterns composed of circular nanohole miniarrays in metal films. This paper presents a study on the spectral and near-field effects of complex rectangular patterns consisted of a central nanoring and slightly rotated satellite nanocrescents in azimuthal orientations, which promote coupling between localized and propagating plasmons. To inspect the localized modes separately, we investigate the spectral responses and near-field phenomena of hexagonal patterns composed of uniform nanorings and nanocrescents, which can be fabricated by a single, homogeneous, circularly polarized beam incident perpendicularly and obliquely, respectively. To understand the interaction of localized and propagating modes, we analyze artificial rectangular patterns composed of a singlet nanoring, a singlet horizontal nanocrescent, and a quadrumer of four slightly rotated nanocrescents. The results demonstrate that on the rectangular pattern of a singlet horizontal nanocrescent the interacting C2 and C1 localized resonances in the C orientation ($$0^{\circ }$$ 0 ∘ azimuthal angle) and the U localized resonance coupled with propagating surface plasmon polaritons (SPPs) in the U orientation ($$90^{\circ }$$ 90 ∘ azimuthal angle) manifest themselves in similar split spectra. Moreover, split spectra appear due to the coupling of the azimuthal orientation independent localized resonance on the nanorings and the SPPs propagating on their rectangular pattern in the U orientation. The spectral response of the complex miniarray pattern can be precisely tuned by varying the geometrical parameters of the moderately interacting nanoholes and the pattern period. In appropriate configurations, the fluorescence of the dipolar emitters is enhanced, which has potential applications in bio-object detection.
Plasmonic nanoresonators of core–shell composition and nanorod shape were optimized to tune their absorption cross-section maximum to the central wavelength of a short laser pulse. The number density distribution of randomly located nanoresonators along a laser pulse-length scaled target was numerically optimized to maximize the absorptance with the criterion of minimal absorption difference between neighboring layers illuminated by two counter-propagating laser pulses. Wide Gaussian number density distribution of core–shell nanoparticles and nanorods enabled to improve the absorptance with low standard deviation; however, the energy deposited until the overlap of the two laser pulses exhibited a considerable standard deviation. Successive adjustment resulted in narrower Gaussian number density distributions that made it possible to ensure almost uniform distribution of the deposited energy integrated until the maximal overlap of the two laser pulses. While for core–shell nanoparticles the standard deviation of absorptance could be preserved, for the nanorods it was compromised. Considering the larger and polarization independent absorption cross-section as well as the simultaneously achievable smaller standard deviation of absorptance and deposited energy distribution, the core–shell nanoparticles outperform the nanorods both in optimized and adjusted nanoresonator distributions. Exception is the standard deviation of deposited energy distribution considered for the complete layers that is smaller in the adjusted nanorod distribution. Optimization of both nanoresonator distributions has potential applications, where efficient and uniform energy deposition is crucial, including biomedical applications, phase transitions, and even fusion.
Application of circularly polarized beams in interferometric illumination of colloid sphere monolayers enables the direct fabrication of rectangular patterns consisting of circular nanohole miniarrays in metal films. The spectral and near-field effects of complex rectangular patterns made of a central nanoring and slightly rotated satellite nanocrescents were studied in azimuthal orientations promoting the localized and propagating plasmons coupling. To inspect the localized modes separately, spectral responses and near-field phenomena of hexagonal patterns composed of uniform nanorings and nanocrescents, that can be fabricated by a perpendicularly and obliquely incident single homogeneous circularly polarized beam, were investigated. To uncover the interaction of localized and propagating modes, artificial rectangular patterns composed of a singlet nanoring, singlet horizontal nanocrescent and quadrumer of four slightly rotated nanocrescents were analyzed. It was demonstrated that the interacting C2 and C1 localized resonances on the (approximately) horizontal nanocrescents in C orientation ((16 • ) 0 • azimuthal
Spectral engineering was realized by tailoring complex patterns of spherical plasmonic nanoresonators achievable via integrated lithography. Enhancement of lasing was demonstrated on Babinet-complementary complex patterns, with multiple spectral peaks at the plasmonic resonances and gaps.
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