Tuning
the surface energetics, especially work function (ϕ)
of the materials, is of a great deal of interest for a wide range
of surface- and interface-based devices and applications. How the
ϕ of a solid surface changes under the reaction conditions is
of paramount interest to the chemists, particularly in the areas of
surface-dependent phenomena such as, catalysis and electrochemistry.
In the present study, by using the valence band and core-level photoelectron
spectroscopy, surface electronic changes from Mo to MoO3 via MoO2 was studied under relevant near-ambient pressure
(NAP) and high temperature conditions. A very significant change in
ϕ from Mo to MoO3 was observed and it is well corroborated
with the changes in gas-phase vibrational features of O2 in both near-ambient pressure ultraviolet photoelectron spectra
(NAPUPS) as well in NAP X-ray photoelectron spectroscopy. Reversible
changes in the electronic structure is observed when MoO3 was reduced in H2 to MoO2. On the basis of
the extent of oxidation/reduction of MoO
x
, NAPUPS has shown, one or two additional peaks in the band gap at
0.6 and 1.6 eV below the Fermi level. Mo5+ features are
identified in the VB and in the Mo 3d core levels with distinct features.
Mo5+ features are also stable and essential to bridge MoO2 and MoO3 layers, and their co-existence. In addition,
characteristic changes in Mo 4d and O 2p features observed from Mo
to MoO3 and well corelated to the band gap of MoO3. Oxidation and reduction propagate from the surface to bulk; indeed,
this has significant implications in surface-dependent phenomena.
The present study demonstrates (a) the uniqueness of NAPUPS in identifying
the subtle to large changes in the electronic structure on solid surfaces
under common oxidation and reduction (in general, under reaction)
conditions, and (b) relevance of NAPUPS to all surface-dependent phenomena,
such as catalysis and electrochemistry.
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