NiTi shape memory alloys (SMAs), as smart materials, are broadly used in medical implants and appliances despite the presence of toxic Ni. In this study, NiTiNb alloys were produced using the substitution of biocompatible Nb instead of Ni. The arc-melting method was utilized to make five SMA samples comprising Ni (29Àx) Ti 50 Nb (21+x ) (x = 0, 1, 2, 3, and 4); then, the phase transformation temperatures, microstructures, crystal structures, and chemical compositions were investigated by DSC, optical microscopy, XRD, and EDX measurements, respectively. The DSC results showed that the samples had a wide hysteresis with the B19¢MB2 phase transformation and martensite start temperatures below room temperature, which makes them suitable for superelastic implants. The presence of dissolved Nb in the matrix of the alloys was the main reason for the widening of temperature hysteresis. When the XRD and SEM results were examined, the b-rich, B2, B19¢, and Ti 2 Ni phases were observed in all samples. Additionally, the main constituent in the dendritic microstructures was Nb.
Recently, there has been a great demand for boron‐containing compounds (BCCs) with unique biological properties. The demand for the use of these compounds not alone but as additives in composite materials is increasing day by day. In this study, the effect of adding B2O3 compound to the blend of PLA and PEG polymers, which is an important biocompatible shape memory polymer, was investigated. In order to examine the effect of increasing B2O3 additive on the thermal properties of PLA‐PEG blend, it was determined by using a Differential Scanning Calorimetry (DSC) and thermogravimetric analyzer (TGA), and it was seen that while the melting temperature of PEG decreased, the melting temperature of PLA increased. In addition, when the thermal stability of the composites was examined, increasing of thermal stability was observed with the addition of B2O3 and a three‐step degradation occurred. It was determined that the B2O3/PLA‐PEG composite was homogeneous by taking X‐ray measurements and SEM measurements. The antimicrobial property of the PLA‐PEG blend improved with the increasing B2O3 contribution were observed from the antimicrobial activity measurements of the composite against 4 different bacteria. However, it was determined that the PLA‐PEG blend preserved its shape memory effect with increasing diboron trioxide contribution.
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