International audienceThe quantification and integration of ecosystem services (ES) into urban planning decisions is becoming increasingly important. However, studies that quantify and analyze the impacts in terms of ES changes are still scarce. We analyzed multiple ES provided by the landscape of the Urban Community of Bordeaux (CUB), in France, between 1990 and 2006 as a result of land use and cover change (LUCC) with Corine Land Cover and other open data. These ES were selected with the help of local stakeholders and were calculated using a spatially explicit modeling approach with InVEST and own-produced models. It was found that all ES, except erosion regulation, have decreased as a consequence of LUCC. Results also suggest that LUCC change decisions which do not consider policy measures for ES protection tend to generate land use patterns providing lower levels of ES. This spatial explicit approach to ES modeling enables an informed discussion with stakeholders and may be used to effectively implement, monitor, and communicate future planning policies
Comprehensive source and fate studies of pharmaceuticals in the environment require analytical methods able to quantify a wide range of molecules over various therapeutic classes, in aqueous and solid matrices. Considering this need, the development of an analytical method to determine 53 pharmaceuticals in aqueous phase and in solid matrices using a combination of microwave-assisted extraction, solid phase extraction, and liquid chromatography coupled with tandem mass spectrometry is reported. Method was successfully validated regarding linearity, repeatability, and overall protocol recovery. Method detection limits (MDLs) do not exceed 1 ng L(-1) for 40 molecules in aqueous matrices (6 ng L(-1) for the 13 remaining), while subnanogram per gram MDLs were reached for 38 molecules in solid phase (29 ng g(-1) for the 15 remaining). Losses due to preparative steps were assessed for the 32 analytes associated to their labeled homologue, revealing an average loss of 40 % during reconcentration, the most altering step. Presence of analytes in wastewater treatment plant (WWTP) effluent aqueous phase and suspended solids (SS) as well as in river water, SS, and sediments was then investigated on a periurban river located in the suburbs of Bordeaux, France, revealing a major contribution of WWTP effluent to the river contamination. Sorption on river SS exceeded 5 % of total concentration for amitriptyline, fluoxetine, imipramine, ritonavir, sildenafil, and propranolol and appeared to be submitted to a seasonal influence. Sediment contamination was lower than the one of SS, organic carbon content, and sediment fine element proportion was accountable for the highest measured concentrations.
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