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Based on low temperature resistivity, heat capacity and magnetization investigations we show that the unusually strong suppression of superconductivity in LuxZr1−xB12 BSC-type superconductors in the range x<0.08 is caused by the emergence of static spin polarization in the vicinity of nonmagnetic lutetium impurities. The analysis of received results points to a formation of static magnetic moments with µ ef f ≈3µB per Lu-ion. The size of these spin polarized nanodomains was estimated to be about 5Å.

Electron spin resonance (ESR) in strongly correlated metals is an exciting phenomenon, as strong spin fluctuations in this class of materials broaden extremely the absorption line below the detection limit. In this respect, ESR observation in CeB6 provides a unique chance to inspect Ce3+ magnetic state in the antiferroquadrupole (AFQ) phase. We apply the original high frequency (60 GHz) experimental technique to extract the temperature and angular dependences of g-factor, line width and oscillating magnetization. Experimental data show unambiguously that the modern ESR theory in the AFQ phase considering the Γ8 ground state of Ce3+ ion completely fails to predict both the g-factor magnitude and its angular dependence. Alignment of the external magnetic field along [100] axis induces a strong (more than twofold) broadening of ESR line width with respect to the other crystallographic directions and results also in the anomalous temperature dependences of the g-factor and oscillating magnetization. In this experimental geometry the latter parameter surprisingly exceeds total static magnetization by 20% at T* ~ 2.5 K. We argue that the unusual physical picture of ESR in CeB6 may be strongly affected by spin fluctuations and dynamic collective effects predominantly pronounced in [100] direction.

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