Electron emission from Ag and Au nanoparticle films was studied under excitation with femtosecond-laser pulses with photon energies of 1.55 and 3.1 eV. Films were grown on a glass substrate with particle sizes from the nanometer range to a continuous layer. The transition from a continuous film to a nanoparticle film is accompanied by an increase in photoemission current by more than an order of magnitude. Pump-and-probe experiments with variable delay gave information on the lifetime of the intermediate states. At a fixed pulse power, the emission yield increases as the temporal width of the laser pulses is decreased. Experimental results are interpreted in terms of two different electron emission mechanisms, i.e., multiphoton photoemission and thermionic emission or thermally assisted multiphoton photoemission. The first mechanism prevails for continuous films and larger particles with sizes above several tens of nanometers; the second one prevails for smaller nanoparticles with sizes of a few nanometers.
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