Nature routinely produces nanostructured surfaces with useful properties, such as the self-cleaning lotus leaf, the colour of the butterfly wing, the photoreceptor in brittlestar and the anti-reflection observed in the moth eye. Scientists and engineers have been able to mimic some of these natural structures in the laboratory and in real-world applications. Here, we report a simple aperiodic array of silicon nanotips on a 6-inch wafer with a sub-wavelength structure that can suppress the reflection of light at a range of wavelengths from the ultraviolet, through the visible part of the spectrum, to the terahertz region. Reflection is suppressed for a wide range of angles of incidence and for both s- and p-polarized light. The antireflection properties of the silicon result from changes in the refractive index caused by variations in the height of the silicon nanotips, and can be simulated with models that have been used to explain the low reflection from moth eyes. The improved anti-reflection properties of the surfaces could have applications in renewable energy and electro-optical devices for the military.
Tuning to G(O) flat: Photoluminescence in graphene oxide (GO) suspensions can be tuned from red to blue emission (see scheme) by gradually changing the amounts of sp2‐ and sp3‐bonded carbon atoms through reduction of the surface oxide groups. Electron–hole recombination from two different types of excited states is proposed to explain the luminescence in GO at varying degrees of reduction.
Photocatalytic conversion of carbon dioxide (CO(2)) to hydrocarbons such as methanol makes possible simultaneous solar energy harvesting and CO(2) reduction, two birds with one stone for the energy and environmental issues. This work describes a high photocatalytic conversion of CO(2) to methanol using graphene oxides (GOs) as a promising photocatalyst. The modified Hummer's method has been applied to synthesize the GO based photocatalyst for the enhanced catalytic activity. The photocatalytic CO(2) to methanol conversion rate on modified graphene oxide (GO-3) is 0.172 μmol g cat(-1) h(-1) under visible light, which is six-fold higher than the pure TiO(2).
Flexible supercapacitors, a state-of-the-art material, have emerged with the potential to enable major advances in for cutting-edge electronic applications. Flexible supercapacitors are governed by the fundamentals standard for the conventional capacitors but provide high flexibility, high charge storage and low resistance of electro active materials to achieve high capacitance performance. Conducting polymers (CPs) are among the most potential pseudocapacitor materials for the foundation of flexible supercapacitors, motivating the existing energy storage devices toward the future advanced flexible electronic applications due to their high redox active-specific capacitance and inherent elastic polymeric nature. This review focuses on different types of CPs-based supercapacitor, the relevant fabrication methods and designing concepts. It describes recent developments and remaining challenges in this field, and its impact on the future direction of flexible supercapacitor materials and relevant device fabrications.
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