The aim of this research was to investigate the cause of the severe localised corrosion that sometimes occurs at welds in carbon steel pipelines carrying hydrocarbons and inhibited brines saturated with carbon dioxide. A rotating cylinder electrode apparatus was designed so that electrodes machined from the weld metal, heat affected zone and parent material of welded X65 pipeline steel could be galvanically coupled and tested in high shear stress conditions. The galvanic currents flowing between the weld regions were recorded using zero resistance ammeters, and their self-corrosion rates were found by polarisation resistance measurements. The total corrosion rate of each weld region was obtained from the sum of the self-corrosion and galvanic contributions. In uninhibited conditions, the weld metal and heat affected zone were both cathodic to the parent material, and localised corrosion was prevented. However, when an oilfield corrosion inhibitor was present, a current reversal took place, which resulted in accelerated weld corrosion. Electrochemical impedance spectroscopy showed that the inhibitor film had lower electrical resistance and was less protective on the weld metal than on the parent material. At the highest shear stress, a second current reversal could occur when the inhibitor was removed from all regions of the weld, and there was a return to the original galvanic behaviour. It was concluded that preferential weld corrosion was caused by unstable conditions in which the inhibitor film was selectively disrupted on the weld metal but remained effective on the other weld regions.
Since centrifugal pumps consume a mammoth amount of energy in various industrial applications, their design and optimization are highly relevant to saving maximum energy and increasing the system’s efficiency. In the current investigation, a centrifugal pump has been designed and optimized. The study has been carried out for the specific application of transportation of slurry at a flow rate of m3/hr to a head of 20 m. For the optimization process, a multi-objective genetic algorithm (MOGA) and response surface methodology (RSM) have been employed. The process is based on the mean line design of the pump. It utilizes six geometric parameters as design variables, i.e., number of vanes, inlet beta shroud, exit beta shroud, hub inlet blade draft, Rake angle, and the impeller’s rotational speed. The objective functions employed are pump power, hydraulic efficiency, volumetric efficiency, and pump efficiency. In this reference, five different software packages, i.e., ANSYS Vista, ANSYS DesignModeler, response surface optimization software, and ANSYS CFX, were coupled to achieve the optimized design of the pump geometry. Characteristic maps were generated using simulations conducted for 45 points. Additionally, erosion rate was predicted using 3-D numerical simulations under various conditions. Finally, the transient behavior of the pump, being the highlight of the study, was evaluated. Results suggest that the maximum fluctuation in the local pressure and stresses on the cases correspond to a phase angle of 0°–30° of the casing that in turn corresponds to the maximum erosion rates in the region.
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