This paper reports the results from a second characterisation of the 91500 zircon, including data from electron probe microanalysis, laser ablation inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS), secondary ion mass spectrometry (SIMS) and laser fluorination analyses. The focus of this initiative was to establish the suitability of this large single zircon crystal for calibrating in situ analyses of the rare earth elements and oxygen isotopes, as well as to provide working values for key geochemical systems. In addition to extensive testing of the chemical and structural homogeneity of this sample, the occurrence of banding in 91500 in both backscattered electron and cathodoluminescence images is described in detail. Blind intercomparison data reported by both LA‐ICP‐MS and SIMS laboratories indicate that only small systematic differences exist between the data sets provided by these two techniques. Furthermore, the use of NIST SRM 610 glass as the calibrant for SIMS analyses was found to introduce little or no systematic error into the results for zircon. Based on both laser fluorination and SIMS data, zircon 91500 seems to be very well suited for calibrating in situ oxygen isotopic analyses.
We report on the detection by Swift of GRB 080913, and subsequent optical/near-infrared follow-up observations by GROND which led to the discovery of its optical/NIR afterglow and the recognition of its high-z nature via the detection of a spectral break between the i and z bands. Spectroscopy obtained at the ESO-VLT revealed a continuum extending down to λ = 9400Å, and zero flux for 7500Å < λ < 9400Å, which we interpret as the onset of a Gunn-Peterson trough at z=6.695±0.025 (95.5% conf. level), making GRB 080913 the highest redshift GRB to date, and more distant than the highest-redshift QSO. We note that many redshift indicators which are based on promptly available burst or afterglow properties have failed for GRB 080913. We report on our follow-up campaign and compare the properties of GRB 080913 with bursts at lower redshift. In particular, since the afterglow of this burst is fainter than typical for GRBs, we show that 2 m-class telescopes can identify most high-redshift GRBs.
Samples of the carbonaceous asteroid Ryugu were brought to Earth by the Hayabusa2 spacecraft. We analyzed seventeen Ryugu samples measuring 1-8 mm. CO
2
-bearing water inclusions are present within a pyrrhotite crystal, indicating that Ryugu’s parent asteroid formed in the outer Solar System. The samples contain low abundances of materials that formed at high temperatures, such as chondrules and Ca, Al-rich inclusions. The samples are rich in phyllosilicates and carbonates, which formed by aqueous alteration reactions at low temperature, high pH, and water/rock ratios < 1 (by mass). Less altered fragments contain olivine, pyroxene, amorphous silicates, calcite, and phosphide. Numerical simulations, based on the mineralogical and physical properties of the samples, indicate Ryugu’s parent body formed ~ 2 million years after the beginning of Solar System formation.
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