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The electronic and excitonic structures of an inorganic–organic perovskite-type quantum-well crystal (C4H9NH3)2PbBr4 have been investigated by optical absorption, photoluminescence, electroabsorption, two-photon absorption, and magnetoabsorption spectroscopies. Excitons in (C4H9NH3)2PbBr4 are of the Wannier-type, and ns (n≥2) excitons form an ideal two-dimensional Wannier exciton system. The binding energy, longitudinal–transverse splitting energy, and exchange energy of 1s excitons have been determined to be 480, 70 and 31 meV, respectively. These high values originate from both a strong two-dimensional confinement and the image charge effect. These values are larger than those in (C6H13NH3)2PbI4, owing to the smaller dielectric constant of the well layer in (C4H9NH3)2PbBr4 than that in (C6H13NH3)2PbI4. The seemingly unusual electric-field dependence of excitons resonance is also reasonably understood by taking the image charge effect into account.

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Exciton characteristics of GaTe single crystals grown by vapor-phase transport were studied by optical measurements. A hydrogenlike exciton series up to nϭ4 was clearly observed in the absorption spectra at 2 K. In the nϭ1 exciton energy region three types of exciton lines were found. By analyzing microphotoluminescence and micro-Raman-scattering spectra on the basis of group theory, it was clarified that these exciton lines are not due to different polytypes but to intrinsic exciton states. Furthermore, optical-absorption spectra in a magnetic field at 4.2 K were measured. In the Voigt configuration, one and two components for Eʈb and EЌb polarizations, respectively, were observed in the nϭ1 and 2 exciton lines. These magnetic-field dependencies cannot be interpreted on the basis of the previously proposed L-S coupling regime. The electronic band structure of GaTe was studied by the ab initio tight-binding linear muffin-tin orbitals method. It was found that GaTe is a direct-gap semiconductor and that the band edge is located at an M point of the Brillouin zone. From a comparison of exciton absorption spectra and the calculated band structure, the existence of the three types of excitons was interpreted from the viewpoint of j-j coupling. Our model calculation was also able to explain the Zeeman splitting and the diamagnetic shift of the exciton peak energies.