Palladium and platinum(II) complexes [MX 2 {CtNC 6 H 2 (3,4,5-OC n H 2n+1 ) 3 } 2 ] (X ) Cl, Br, I; n ) 4, 6, 8, 10, 12) have been prepared. The free isocyanides are not liquid crystals, but most of their complexes [MX 2 {CtNC 6 H 2 (3,4,5-OC n H 2n+1 ) 3 } 2 ] (M ) Pd, Pt; X ) Cl, Br, I) show hexagonal columnar phases. For M ) Pd and X ) Cl and Br, an isomerization is observed going from the condensed phases to the solution. In the mesophase all the complexes seem to be cis for X ) Cl and Br and trans for X ) I. Their melting points depend mostly on the peripheral chains and are little sensitive to the configuration cis or trans or to the metal (Pd or Pt). The clearing points depend more on the core interactions and show noticeable variations (cis > trans; Pt > Pd). The reasons for this behavior are discussed.

The geometry imposed by the coordination sphere around the metal, together with the choice of the "arms" can be advantageously used to build corannulene-based molecular tweezers, which show great affinities for C60 and C70, as revealed by NMR titration experiments, mass spectroscopy, DFT calculations and the single crystal X-ray structural analysis of the compound C60 ⊂1.