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Weak inter-or intramolecular interactions, especially when combined and integrated into appropriate molecular "architecture", can lead to the formation of supramolecular structures with specific functionality."] Here we report a system that, owing to such interactions in the solid, shows strong luminescence from a metal-to-ligand charge-transfer (MLCT) excited state.Compounds 1-3, which belong to the class of homodinuclear complexes containing the bridging ligand 2,T-bipyriml a