Gasification reaction behavior of iron coke as well as kinetic parameters is extremely important for its quality evaluation and practical application in an actual blast furnace. However, there are few researches on the gasification behavior of iron coke, especially for iron coke hot briquette (ICHB) prepared by hot briquetting process. In this paper, the gasification reaction behavior of ICHB is experimentally investigated under isothermal conditions. Meanwhile, the kinetic analysis for the gasification process of ICHB and the related mechanism are carried out. The results demonstrate that the increase of the reaction temperature causes the significant rise of the carbon conversion rate and the reaction rate of ICHB, while the post‐reaction strength is evidently decreased. The size degradation of ICHB after reaction is increasingly serious as the reaction temperature goes up, and more pores as well as cracks are generated inside the gasified ICHB. During the gasification, the reduction of iron oxide, the oxidization of metal iron, and the generation reaction of fayalite are concomitantly occurred. The most probable mechanism function is confirmed. Based on this model, the activation energy and pre‐exponential factor are conducted, which are 144.77 kJ mol−1 and 999.37 min−1, respectively.
Utilization of iron carbon agglomerates (ICA) with high reactivity in blast furnace (BF) can reduce fuel ratio and carbon emission by decreasing the temperature of thermal reserve zone, which is considered to be an innovative technology for achieving low-carbon ironmaking. Herein, the influences of coal tar pitch (CTP) as binder on the metallurgical properties of ICA are investigated. The results show that the compressive strength of ICA is first enhanced from 1639 to 3168 N and then reduced to 2243 N with the ratio of CTP increasing from 0% to 11%. Meanwhile, the drum strength (I 600 10 ) of ICA is accelerated from 67.3% to 80.5% and then leveled off. In addition, the reactivity of ICA is mitigated from 65.6% to 58.1% first and then increased to 68.8%, while the post-reaction strength shows an inverse trend. When the ratio of CTP is 5-7%, the mechanical strength, reactivity, and post-reaction of ICA are all at a relatively better levels. For the ICA with adding CTP, the mechanical strength is dependent on the microstructure, pore volume, and specific surface area, whereas the variation of reactivity and post-reaction strength are relevant to the pore structure and carbon crystallites structure.
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