State-of-the-art external quantum efficiencies (EQEs) have exceeded 20% for near-infrared, red, and green perovskite light-emitting diodes (PeLEDs) so far. Nevertheless, the cutting-edge blue counterparts demonstrate an inferior device performance, which impedes the commercialization and industrialization of PeLEDs in ultrahigh-definition displays. As the most popular hole transport layer, poly­(3,4-ethylenedioxythiophene):polystyrenesulfonate (PEDOT:PSS) bears the acidic and hygroscopic drawbacks, which deteriorates the device efficiency and long-term stability of blue PeLEDs. In this work, the basic amino acids with zwitterionic characteristics are proposed to modulate the pH of PEDOT:PSS, which are arginine, lysine, and histidine. It is found that they play a triple function to the blue perovskite films: modulating the acidity of PEDOT:PSS, controlling the crystalline process, and passivating the defects at the PEDOT:PSS/perovskite interface. As a result, the utilization of neutral PEDOT:PSS leads to a significant enhancement in stability and photoluminescence quantum yield. Eventually, the pure-blue PeLEDs achieve a record EQE of 5.6% with the emission peak at 467 nm. This research proves that the interfacial engineering of hole transport layers is a reliable strategy to enhance the device efficiency and operation stability of blue PeLEDs.

Underwater wireless optical communication (UWOC) has been widely considered a supplement to traditional underwater acoustic communication. A real-time UWOC video delivery system was developed in a laboratory water tank based on a field-programmable gate array (FPGA) with binary frequency shift keying (2FSK) modulation. The system achieved full-duplex communication by using the transmission control protocol (TCP) and forward error correction (FEC). A high-power 445 nm lightemitting diode (LED) array was adopted to enhance the transmitted optical power and increase the transmission link distance. We present an underwater optical channel model that considers the effects of both geometry and channel loss, especially considering the impact of the refractive index of the optical medium and the non-line-of-sight (NLOS) links formed by water surface reflection. MATLAB was used to simulate this channel model and predict the received optical power distribution on the receiving plane. Additionally, we propose improved calculation methods for the consumed electrical power and transmitted optical power of the LED array. We also investigate the relationship between the optimum avalanche gain of an avalanche photodiode (APD) and the signal-to-noise ratio (SNR). This full-duplex system achieved a 1 Mbps data transmission rate at an SNR of 10.1 dB and a distance of 10 m for an underwater link. In addition, when the optical power of the LED array is enhanced, the link range is predicted to be 14.5 m with an attenuation coefficient of 0.056 /m. INDEX TERMS Binary frequency shift keying, full-duplex, FPGA, high-power LED array, optical link model, Reed-Solomon code, underwater wireless optical communication. I. INTRODUCTION The ocean is the cradle of life. Approximately 71% of the Earth's surface is covered by the ocean. The vast marine resources on Earth are indispensable for many aspects of life. It is necessary to exploit and utilize those resources with underwater wireless communication (UWC) technology, which has considerable potential in facilitating the use of underwater vehicles, devices, observatories, and sensors. Underwater wired communication uses fiber optic or copper cable, which is expensive, inflexible, and vulnerable to marine life, making it largely infeasible for use in underwater mobile systems. Acoustic waves, radio frequency (RF) waves, and optical waves are three primary physical information carriers for underwater wireless information transmission [1]-[3]. Acoustic waves involve mechanical waves with relatively little attenuation underwater (0.1-4 dB/km), and thus, they can cover long distances up to dozens of kilometers. However, acoustic waves have a low propagation speed (1500 m/s) and limited bandwidth (kHz), which leads to a multipath phenomenon, large time latency, and bulky antennas [2]. These characteristics hinder the application of acoustic waves in real-time and bandwidth-intensive scenarios. RF waves are another carrier that can provide a high data rate (Mbps), high bandwidth (MHz), and high speed...

Underwater wireless optical communication (UWOC) is a promising technology that can be a candidate to improve the communication capacity and speed in aquatic media. The aim of this study is to examine the performance of a silicon photomultiplier (SiPM) array-based multiple-input multiple-output (MIMO) UWOC system. A SiPM is a modern solid-state photodetector with extremely high sensitivity up to the single-photon level or a photon-counting ability, which helps in detecting extremely weak light signals after long-distance underwater channel attenuation. We clarify the basic characteristics and photon-counting detection mode of a SiPM. In particular, the photocount of a SiPM is approximated by a Gaussian distribution, and theoretical analysis shows that only 13.3 photons need to be detected during “1” symbol period to achieve a bit error rate of 10−3 in an ambient light environment. Moreover, a SiPM also has a better analog mode detection ability than an avalanche photodiode (APD) and realizes 2 Mbps analog communication owing to its unique array structure and high photon detection efficiency. Furthermore, MIMO, i.e., spatial diversity, is applied as an effective method to relax the link alignment, improve the system performance, and alleviate the effect of optical turbulence. In our experiment, with a photon-counting 6×3 MIMO scheme, an energy per bit of 7.38×10−9 J/bit is achieved at a scintillation index of 4.66×10−3 in a 10 m water tank with 1 Mbps on-off-keying (OOK) modulation. To the best of our knowledge, this is the first study on a MIMO-UWOC system based on the photon-counting mode of a SiPM array. This UWOC system combines the advantages of SiPMs and the MIMO scheme and has the potential to realize long-distance UWOC under optical turbulence.

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Flexible perovskite light-emitting diodes (PeLEDs) constitute an emerging technology opening new opportunities in the fields of lighting and display for portable and wearable electronics. Poly(3,4-ethylenedioxythiophene):poly-(stryrenesulfonate) (PEDOT:PSS) as one of the most promising flexible electrode materials has attracted extensive attention. However, the patterning and conductivity issues of PEDOT:PSS electrodes should be addressed primarily. Here, a photopolymerizable additive is proposed to endow the PEDOT:PSS electrodes with photopatternability. Moreover, this additive can also improve the conductivity of the PEDOT:PSS electrode from 0.16 to 627 S/cm because of the phase separation between PEDOT and PSS components and conformation transition of PEDOT chains. Eventually, highly conductive PEDOT:PSS electrodes with various patterns are applied in flexible PeLEDs, demonstrating a high luminance of 25972 cd/m 2 and a current efficiency of 25.1 cd/A. This work provides a facile and effective method of patterning and improving the conductivity of PEDOT:PSS electrodes simultaneously, demonstrating the great potential of PEDOT:PSS electrodes in flexible perovskite optoelectronics.