A high-temperature stable broadband plasmonic absorber is designed, fabricated, and optically characterized. A broadband absorber with an average high absorption of 95% and a total thickness of 240 nm is fabricated, using a refractory plasmonic material, titanium nitride. This absorber integrates both the plasmonic resonances and the dielectric-like loss. It opens a path for the interesting applications such as solar thermophotovoltaics and optical circuits.
Light, as an external stimulus, is capable of driving the motion of micro/nanomotors (MNMs) with the advantages of reversible, wireless and remote manoeuvre on demand with excellent spatial and temporal resolution. This review focuses on the state-of-the-art light-driven MNMs, which are able to move in liquids or on a substrate surface by converting light energy into mechanical work. The general design strategies for constructing asymmetric fields around light-driven MNMs to propel themselves are introduced as well as the photoactive materials for light-driven MNMs, including photocatalytic materials, photothermal materials and photochromic materials. Then, the propulsion mechanisms and motion behaviors of the so far developed light-driven MNMs are illustrated in detail involving light-induced phoretic propulsion, bubble recoil and interfacial tension gradient, followed by recent progress in the light-driven movement of liquid crystalline elastomers based on light-induced deformation. An outlook is further presented on the future development of light-driven MNMs towards overcoming key challenges after summarizing the potential applications in biomedical, environmental and micro/nanoengineering fields.
Intelligent photoresponsive isotropic semiconductor micromotors are developed by taking advantage of the limited penetration depth of light to induce asymmetrical surface chemical reactions. Independent of the Brownian motion of themselves, the as-proposed isotropic micromotors are able to continuously move with both motion direction and speed just controlled by light, as well as precisely manipulate particles for nanoengineering.
In this work, we have demonstrated the autonomous motion of biologically-friendly Mg/Pt-Poly(N-isopropylacrylamide) (PNIPAM) Janus micromotors in simulated body fluids (SBF) or blood plasma without any other additives. The pit corrosion of chloride anions and the buffering effect of SBF or blood plasma in removing the Mg(OH)2 passivation layer play major roles for accelerating Mg-H2O reaction to produce hydrogen propulsion for the micromotors. Furthermore, the Mg/Pt-PNIPAM Janus micromotors can effectively uptake, transport, and temperature-control-release drug molecules by taking advantage of the partial surface-attached thermoresponsive PNIPAM hydrogel layers. The PNIPAM hydrogel layers on the micromotors can be easily replaced with other responsive polymers or antibodies by the surface modification strategy, suggesting that the as-proposed micromotors also hold a promising potential for separation and detection of heavy metal ions, toxicants, or proteins.
After the tremendous advances over the past two decades, micro‐/nanorobots can effectively convert other forms of energy into propulsion and movement, as well as be navigated to targeted locations under physiological conditions and environments. They have been demonstrated to have the potential to load, transport, and deliver therapeutic payloads directly to disease sites, thereby improving the therapeutic efficacy and reducing systemic side effects of highly toxic drugs. In this feature article, the various propulsion modalities of micro‐/nanorobots ranging from chemical/biochemical reactions to external fields, and to motile microorganisms are summarized and commented in terms of driving forces required by the automotive motion in biological media, biocompatibility, as well as the corresponding advantages and limitations in terms of biomedical applications. Then, the latest developments of in vitro and in vivo active drug delivery based on micro‐/nanorobots are discussed in detail. The challenges and future prospects are also highlighted in the end. With ever booming research enthusiasm in this field and increasing multidisciplinary cooperation, micro‐/nanorobots with intelligence and multifunctions will emerge in the near future, which would have a profound impact on the treatment of diseases.
In this work, light-controlled bubble-propelled single-component metal oxide tubular microengines have for the first time been demonstrated. For such a simple single-component TiO2 tubular microengine in H2O2 aqueous solution under UV irradiation, when the inner diameter and length of the tube are regulated, the O2 molecules will nucleate and grow into bubbles preferentially on the inner concave surface rather than on the outer surface, resulting in a vital propulsion of the microengine. More importantly, the motion state and speed can be modulated reversibly, fast (the response time is less than 0.2 s) and wirelessly by adjusting UV irradiation. Consequently, the as-developed TiO2 tubular microengine promises potential challenged applications related to photocatalysis, such as "on-the-fly" photocatalytic degradation of organic pollutes and photocatalytic inactivation of bacteria due to the low cost, single component, and simple structure, as well as the facile fabrication in a large-scale.
In this work, water-fuelled TiO2/Pt Janus submicromotors with light-controlled motions have been developed by utilizing the asymmetrical photocatalytic water redox reaction over TiO2/Pt Janus submicrospheres under UV irradiation. The motion state, speed, aggregation and separation behaviors of the TiO2/Pt Janus submicromotor can be reversibly, wirelessly and remotely controlled at will by regulating the "on/off" switch, intensity and pulsed/continuous irradiation mode of UV light. The motion of the water-fuelled TiO2/Pt Janus submicromotor is governed by light-induced self-electrophoresis under the local electrical field generated by the asymmetrical water oxidation and reduction reactions on its surface. The TiO2/Pt Janus submicromotors can interact with each other through the light-switchable electrostatic forces, and hence continuous and pulsed UV irradiation can make the TiO2/Pt Janus submicromotors aggregate and separate at will, respectively. Because of the enhanced mass exchange between the environment and active submicromotors, the separated TiO2/Pt Janus submicromotors powered by the pulsed UV irradiation show a much higher activity for the photocatalytic degradation of the organic dye than the aggregated TiO2/Pt submicromotors. The water-fuelled TiO2/Pt Janus submicromotors developed here have some outstanding advantages as "swimming" photocatalysts for organic pollutant remediation in the macro or microenvironment (microchannels and microwells in microchips) because of their small size, long-term stability, wirelessly controllable motion behaviors and long life span.
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