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We discuss the calculation of crystal-field splittings using Wannier functions and show how contributions to the crystal-field splitting that are due to hybridization with different ligand states can be separated from the bare Coulomb contribution by constructing sets of Wannier functions incorporating different levels of hybridization. We demonstrate this method using SrVO3 as a generic example of a transition metal oxide. We then calculate trends in the crystal-field splitting for two series of hypothetical tetragonally distorted perovskite oxides and discuss the relation between the calculated 'electrostatic' contribution to the crystal field and the simple point charge model. Finally, we apply our method to the charge disproportionated 5d electron system CsAuCl3. The proposed procedure elucidates the way in which the negative charge transfer energy in this material leads to a reversal of the p-d ligand contribution to the crystal-field splitting such that the eg states of the nominally Au(3+) cation are energetically lower than the corresponding t2g states.

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The present set of studies developed and tested the Food Disgust Picture Scale (FDPS). This is a tool for the assessment of food disgust sensitivity that will measure disgust and predict possible reactions. This eight-picture tool can be used in complement to or as a replacement for currently available text-based measures. In an exploratory Study 1 (N = 57), we constructed a scale consisting of eight pictures. Most of them were taken from validated picture databases. They proved powerful in the assessment of food disgust sensitivity. Study 2 built on these results and refined the scale by substituting pictures from Study 1 with freely available images displaying similar content. The basic structure of the FDPS was then replicated in a bigger sample of Swiss adults (N = 538). Correlational analyses using the eight-item Food Disgust Scale (FDS short), the revised version of the Disgust Scale (DS-R), and the food neophobia scale (FNS) supported the convergent validity of the FDPS. In Study 3 (N = 226), we used a test-retest design to demonstrate the short-term stability of the FDPS. As a result of these studies, the present work provides a short and comprehensive measure of food disgust sensitivity. This novel approach of using pictures to induce a disgust response independently of language significantly facilitates intercultural research on disgust. The FDPS will further contribute to the understanding of food-related disgust and its impact on our food choices.