Abstract:The high contents of disadvantageous elements contained in non-woody biomass are known to cause problems during small and large scale combustion, typically resulting in a higher risk of slagging, corrosion, and increased emissions. Mechanically leaching the respective elements from the biomass through a sequence of process steps has proven to be a promising solution. The florafuel process used here is comprised of size reduction followed by washing and subsequent mechanical dewatering of the biomass. Densification of the upgraded biomass into standardized pellets (Ø 6mm) enables an application in existing small-scale boilers. The presented combustion trials investigated the performance of pellets made from leached grass, foliage and a mixture of both in two small-scale boilers (<100 kWth) with slightly different technology (moving grate versus water-cooled burner tube) during a 4-h measurement period. Emissions were in accordance with German emissions standards except for NO x (threshold is 0.50 g/m 3 ) in the case of pure grass pellets (0.51 g/m 3 ) and particulate matter (PM) in all but one case (foliage, 13-16 mg/m 3 ). An electrostatic precipitator (ESP) unit installed with one of the boilers successfully reduced PM emission of both the grass and mixture fuel below the threshold of 20 mg/m 3 (all emission values refer to 13 vol.% O 2 , at standard temperature and pressure (STP)). Bottom ash composition and grate temperature profiles were analyzed and discussed for one of the boilers.

Changes in livestock production systems have led to land‐use changes and abandonment, especially of semi‐natural grassland in agriculturally less favoured regions. The generation of energy from biomass of extensive, high‐diversity grasslands can be an alternative to their abandonment, and anaerobic digestion is one possible method for converting grassland biomass into energy. However, little is known about the effects of species richness (SR) and functional groups on chemical constituents relevant for anaerobic digestion and the resulting energy potential. In this study, changes in the herbage chemical constituents that are relevant for forage quality were studied along a well‐defined diversity gradient (one to sixty species) and across different combinations of functional groups (legumes, small herbs, tall herbs and grasses). Substrate‐specific methane yield (CH4 sub) was estimated through the concentrations of forage‐quality parameters such as crude fibre (CF), crude protein (CP), crude lipid, nitrogen‐free extract and their documented digestibility values, as well as the respective methane yields. Results show that with increasing SR, the CF increased and CP decreased, even though these effects could not be fully disentangled from the presence of grasses. These trends led to a negative effect of SR on CH4 sub, while the area‐specific methane yield (CH4 area = CH4 sub × biomass yield) increased due to a strong increase in biomass with increasing SR. The CH4 sub was increased when legumes were present, and it declined with the presence of grasses. Generally, CH4 sub and CH4 area varied between functional‐group monocultures and all functional‐group mixtures.

Grassland biomass has been identified as a potential energy source. The combustion of mature and fibrous biomass, as occurs in extensive grasslands managed with low cutting frequencies, is one possible conversion technique. This study tested the relationship between plant diversity and biomass constituents relevant for combustion, as they determine energy content, energy yield and emission and corrosion risks. The biomass from a biodiversity experiment, with a species richness (SR) gradient of 1–60 species from Central European mesophilic grasslands divided into four functional groups (grasses, legumes, small and tall herbs), was harvested twice a year (in 2008 and 2009). The higher heating value (HHV) was estimated from carbon, hydrogen and oxygen contents to give insight into the energy potential of the species mixtures. The potential risk of emission and corrosion was assessed by analysing ash content, potassium, calcium, magnesium, nitrogen, sulphur and chloride content. HHV was independent of SR, and the overall mean was 18·13 MJ kg−1 DM. Biomass and gross energy (GE) yield were positively affected by SR. The presence of legumes in a mixture resulted in increased HHV, biomass yield and GE, irrespective of the level of SR. Annual GE varied between 59 (average of monocultures) and 152 GJ ha−1 year−1 (mixture of sixty species). The concentration of ash‐forming elements was generally high, suggesting a pre‐treatment of the biomass prior to combustion. Emission‐ and corrosion‐related constituents were clearly affected by the different functional groups, and sulphur and nitrogen both declined with SR. The results of this study show that high SR in experimental grassland communities is beneficial for the energy output and that legumes play a key role for the energy potential. However, identifying a functional group as being solely beneficial or disadvantageous for fuel quality was difficult.

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Abstract:The firing and co-firing of biomass in pulverized coal fired power plants around the world is expected to increase in the coming years. Torrefaction may prove to be a suitable way of upgrading biomass for such an application. For transport and storage purposes, the torrefied biomass will tend to be in pellet form. Whilst standard methods for the assessment of the milling characteristics of coal exist, this is not the case for torrefied materials-whether in pellet form or not. The grindability of the fuel directly impacts the overall efficiency of the combustion process and as such it is an important parameter. In the present study, the grindability of different torrefied biomass pellets was tested in three different laboratory mill types; cutting mill (CM), hammer mill (HM) and impact mill (IM). The specific grinding energy (SGE) required for a defined mass throughput of pellets in each mill was measured and results were compared to other pellet characterization methods (e.g., durability, and hardness) as well as the modified Hardgrove Index. Seven different torrefied biomass pellets including willow, pine, beech, poplar, spruce, forest residue and straw were used as feedstock. On average, the particle-size distribution width (across all feedstock) was narrowest for the IM (0.41 mm), followed by the HM (0.51 mm) and widest for the CM (0.62 mm). Regarding the SGE, the IM consumed on average 8.23 Wh/kg while CM and HM consumed 5.15 and 5.24 Wh/kg, respectively. From the three mills compared in this study, the IM seems better fit for being used in a standardized method that could be developed in the future, e.g., as an ISO standard.