At su ciently high temperature and energy density, nuclear matter undergoes a transition to a phase in which quarks and gluons are not confined: the quark-gluon plasma (QGP) 1 . Such an exotic state of strongly interacting quantum chromodynamics matter is produced in the laboratory in heavy nuclei high-energy collisions, where an enhanced production of strange hadrons is observed 2-6 . Strangeness enhancement, originally proposed as a signature of QGP formation in nuclear collisions 7 , is more pronounced for multi-strange baryons. Several e ects typical of heavy-ion phenomenology have been observed in high-multiplicity proton-proton (pp) collisions 8,9 , but the enhanced production of multi-strange particles has not been reported so far. Here we present the first observation of strangeness enhancement in high-multiplicity proton-proton collisions. We find that the integrated yields of strange and multi-strange particles, relative to pions, increases significantly with the event charged-particle multiplicity. The measurements are in remarkable agreement with the p-Pb collision results 10,11 , indicating that the phenomenon is related to the final system created in the collision. In high-multiplicity events strangeness production reaches values similar to those observed in Pb-Pb collisions, where a QGP is formed.The production of strange hadrons in high-energy hadronic interactions provides a way to investigate the properties of quantum chromodynamics (QCD), the theory of strongly interacting matter. Unlike up (u) and down (d) quarks, which form ordinary matter, strange (s) quarks are not present as valence quarks in the initial state, yet they are sufficiently light to be abundantly created during the course of the collisions. In the early stages of high-energy collisions, strangeness is produced in hard (perturbative) 2 → 2 partonic scattering processes by flavour creation (gg → ss, qq → ss) and flavour excitation (gs → gs, qs → qs). Strangeness is also created

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The measurement of primary , , and production at mid-rapidity ( 0.5) in proton–proton collisions at 7 TeV performed with a large ion collider experiment at the large hadron collider (LHC) is reported. Particle identification is performed using the specific ionisation energy-loss and time-of-flight information, the ring-imaging Cherenkov technique and the kink-topology identification of weak decays of charged kaons. Transverse momentum spectra are measured from 0.1 up to 3 GeV/ for pions, from 0.2 up to 6 GeV/ for kaons and from 0.3 up to 6 GeV/ for protons. The measured spectra and particle ratios are compared with quantum chromodynamics-inspired models, tuned to reproduce also the earlier measurements performed at the LHC. Furthermore, the integrated particle yields and ratios as well as the average transverse momenta are compared with results at lower collision energies.

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