Quantitative absorption and fluorescence spectroscopy of Cd(CH3)2 in vacuum ultraviolet J. Chem. Phys. 89, 160 (1988); 10.1063/1.455499 Polarizationdependent optical gain and absorption spectra of (Cd,Mn)Te and (Zn,Mn)Se multiple quantum well structures Ultraviolet absorption spectra were recorded for the transient radicals CdCH 3 • ZnCH 3 • and TeCH 3 produced in the flash photolysis of the appropriate _dimeth~ metals. F~r CdC~3 and ZnCH 3 two systems were observed and assigned to the two transitions A 'E<--X 2 At l!nd B 'E<--X 2 At. For the TeCH 3 radical only one system was observed which was assigned to the B<--X transition. The progres~ions in the spectra are assigned to the upper state carbon -metal stretching vibration (v' 3) and CH 3 symmetnc deformation vibrations (v'').
The reactions of ground-state (3P2,i,o) atoms of the group Via elements with olefins have received considerable attention in recent years.1-7 Atomic oxygen yields epoxides, the isomeric carbonyl compounds, and various fragmentation products. Sulfur, selenium, and tellurium give only the cyclic adduct which, with the latter two elements, has only transient existence.
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